异丙基氯化镁氯化锂络合物 溶液

• 产品号: 656984
• 分子式: C3H7Cl2LiMg
• 分子量: 145.23968

产品别名

• 标题: Isopropylmagnesium chloride lithium chloride complex solution
• IUPAC标准名: lithium(1+) ion chloro(propan-2-yl)magnesium chloride
• IUPAC传统名: lithium(1+) ion chloro(isopropyl)magnesium chloride
• 别名: Turbo Grignard

产品登记号

• MDL号: MFCD07784514
• PubChem SID: 24884252

产品性质

• 浓度: 1.3 M in THF
• 线性分子式: (CH3)2CHMgCl · LiCl
• 密度: 0.951 g/mL at 25 °C
• 闪点: -17 °C
• 闪点: 1.4 °F
• GHS警示词: Danger
• GHS危险声明: H225-H314-H335
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 个人保护装置: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P210-P261-P280-P305 + P351 + P338-P310
• RID/ADR: UN 3399 4.3/PG 2
• 危险公开号: 11-14/15-19-34-37
• 安全公开号: 16-26-36/37/39-43-45
• 欧盟补充危害声明: May form explosive peroxides., Reacts violently with water.
• 联合国危险货物等级: 4.3
• 联合国危险货物编号: 3399
• 联合国危险货物包装类别(PG): 2
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Reagent used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.14
Reagent for Selective MetalationsUsed for:
• Preparation of functionalized acyclic alkenyl magnesium reagents/preparation of 1,2-diketones1
• Preparation of cyclic alkenyl and dienyl magnesium reagents2
• Preparation of functionalized triazenes/preparation of carbazoles3
• Regioselective functionalization of trisubstituted pyridines4
• Electrophilic amination for preparation of amines5
• Preparation of Grignards reagents in the presence of masked ketones and aldehydes (using readily deprotectable silylated cyanohydrins)6
• Preparation of Benzylic Grignards via Sulfur-Magnesium exchange7
• Functionalization via I-Mg Exchange of unprotected aromatic and heteroaromatic carboxylic acids8
• Functionalization via I-Mg Exchange of unprotected imidazoles9
• Pyridyne formation10
• Functionalization of cyclopentene derivatives11
• Preparation of 2,3-functionalized furans, benzofurans, and thiophenes12
• Stereoselective synthesis of substituted cyclopropanes13
Packaging
4×25, 100, 800 mL in Sure/Seal™
Legal Information
Product of Rockwood Lithium

详细说明 (简体中文)

Application
Reagent used with CH3MgCl/LiCl to affect magnesium-halogen exchange on unprotected aryl carboxylic acids.14
Reagent for Selective MetalationsUsed for:
• Preparation of functionalized acyclic alkenyl magnesium reagents/preparation of 1,2-diketones1
• Preparation of cyclic alkenyl and dienyl magnesium reagents2
• Preparation of functionalized triazenes/preparation of carbazoles3
• Regioselective functionalization of trisubstituted pyridines4
• Electrophilic amination for preparation of amines5
• Preparation of Grignards reagents in the presence of masked ketones and aldehydes (using readily deprotectable silylated cyanohydrins)6
• Preparation of Benzylic Grignards via Sulfur-Magnesium exchange7
• Functionalization via I-Mg Exchange of unprotected aromatic and heteroaromatic carboxylic acids8
• Functionalization via I-Mg Exchange of unprotected imidazoles9
• Pyridyne formation10
• Functionalization of cyclopentene derivatives11
• Preparation of 2,3-functionalized furans, benzofurans, and thiophenes12
• Stereoselective synthesis of substituted cyclopropanes13
包装
4×25, 100, 800 mL in Sure/Seal™
Legal Information
Product of Rockwood Lithium