(R)-T-BINAP

• 产品号: 693049
• CAS号: 99646-28-3
• 分子式: C48H40P2
• 分子量: 678.778722

产品别名

• 标题: (R)-T-BINAP
• IUPAC标准名: (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane
• IUPAC传统名: (1-{2-[bis(4-methylphenyl)phosphanyl]naphthalen-1-yl}naphthalen-2-yl)bis(4-methylphenyl)phosphane
• 别名: (R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘; (R)-Tol-BINAP; (R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl

产品登记号

• CAS号: 99646-28-3
• MDL号: MFCD01311709

产品性质

• Empirical Formula (Hill Notation): C48H40P2
• 熔点: 250-255 °C
• 熔点: 254-258 °C
• 比旋光度: [α]20/D +162°, c = 0.5 in benzene
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
100, 500 mg in glass bottle
Legal Information
Sold in collaboration with Takasago for research purposes only.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated esterReactant serving as a precursor for:
• Catalysts used for reductive amination of ketones
• Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives
• Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones
• CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters
• BINAP Pt Dications for cation trapping

详细说明 (简体中文)

包装
100, 500 mg in glass bottle
Legal Information
与 Takasago 联合销售，仅供研究使用。
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Catalyst involved in studies of the role of excess phosphine ligand in enantioselective conjugate addition of ethylmagnesium bromide and α,β-unsaturated esterReactant serving as a precursor for:
• Catalysts used for reductive amination of ketones
• Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives
• Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones
• CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters
• BINAP Pt Dications for cation trapping