偶氮二甲酸二乙酯 溶液

• 产品号: 11627
• CAS号: 1972-28-7
• 分子式: C6H10N2O4
• 分子量: 174.1546

产品别名

• 标题: Diethyl azodicarboxylate solution
• IUPAC标准名: N-[(ethoxycarbonyl)imino]ethoxyformamide
• IUPAC传统名: diethyl azodicarboxylate
• 别名: Unifoam AZ-AE 200; Diethoxycarbonyldiazene solution; NSC 679015; Diethyl azodiformate solution; DEAD; 1,2-Ethoxycarbonyl diazene solution; NSC 3474

产品登记号

• MDL号: MFCD00009103
• CAS号: 1972-28-7
• PubChem SID: 24847277
• Beilstein号: 908662

产品性质

• 浓度: ~40% in toluene (H-NMR)
• 级别: purum
• 线性分子式: C2H5OCON=NCOOC2H5
• 闪点: 41 °C
• 闪点: 105.8 °F
• 折射率: n20/D 1.47
• GHS警示词: Danger
• GHS危险声明: H226-H304-H315-H319-H335-H336-H361d-H373
• 欧盟危险性物质标志: 有害性(Harmful) (Xn)
• 个人保护装置: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P261-P281-P301 + P310-P305 + P351 + P338-P331
• RID/ADR: UN 3379 3/PG 1
• 危险公开号: 63-10-20-36/37/38-48/20-65
• 安全公开号: 26-36/37-62
• 保存温度: 2-8°C
• 联合国危险货物等级: 3
• 联合国危险货物编号: 3379
• 联合国危险货物包装类别(PG): 1
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Other Notes
Reagent used in the Mitsunobu reaction, reviews9,10,11
Application
Reactant for preparation of:
• Immunostimulants α-Galactosylceramides1
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases2
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase3
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities4
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes5Reagent for:
• Annulation of N-protected imines6
• α-thiocyanation of enolizable ketones with ammonium thiocyanate7
• Diels-Alder reactions8

详细说明 (简体中文)

Other Notes
用于 Mitsunobu 反应的试剂，综述9,10,11
Application
Reactant for preparation of:
• Immunostimulants α-Galactosylceramides1
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases2
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase3
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities4
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes5Reagent for:
• Annulation of N-protected imines6
• α-thiocyanation of enolizable ketones with ammonium thiocyanate7
• Diels-Alder reactions8