L-Selectride® 溶液

• 产品号: 257044
• CAS号: 38721-52-7
• 分子式: C12H27BLi
• 分子量: 189.09478

产品别名

• 标题: L-Selectride® solution
• IUPAC标准名: lithium(1+) ion tris(butan-2-yl)boranuide
• IUPAC传统名: lithium(1+) ion tris(sec-butyl)boranuide
• 别名: 三仲丁基硼氢化锂 溶液; Lithium tri-sec-butylborohydride solution

产品登记号

• PubChem SID: 24855566
• MDL号: MFCD00011708
• Beilstein号: 4007327
• CAS号: 38721-52-7

产品性质

• 浓度: 1.0 M lithium tri-sec-butylborohydride in THF
• 线性分子式: Li[CH(CH3)CH2CH3]3BH
• 密度: 0.89 g/mL at 25 °C
• 闪点: -17 °C
• 闪点: 1.4 °F
• GHS警示词: Danger
• GHS危险声明: H225-H250-H260-H314-H335
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 个人保护装置: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P210-P222-P223-P231 + P232-P370 + P378-P422
• RID/ADR: UN 3394 4.2/PG 1
• 危险公开号: 11-14/15-17-19-34-37
• 安全公开号: 16-26-36/37/39-43-45
• 欧盟补充危害声明: May form explosive peroxides.
• 联合国危险货物等级: 4.2
• 联合国危险货物编号: 3394
• 联合国危险货物包装类别(PG): 1
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Packaging
1.8 L in Sure-Pac™
200 mL in Sure-Pac™
Application

• Reducing agent1Reagent for:
• Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters2
• Diastereoselective reduction reactions3
• Hydride reduction of the Danishefsky pyranones4
• Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes5
• Synthesis of alkanols by carbonylation reactions6
Recommended products
Angled septum-inlet adapter Z118206 or straight septum-inlet adapter, 6mm I.D. inlet, Z118141 or straight septum-inlet adapter, 13mm I.D. inlet, Z118192 is recommended.
Legal Information
Selectride is a registered trademark of Sigma-Aldrich Co. LLC

详细说明 (简体中文)

包装
1.8 L in Sure-Pac™
200 mL in Sure-Pac™
Application

• Reducing agent1Reagent for:
• Enantioselective synthesis of a-amino acids via reduction of N-tert-butanesulfinyl ketimine esters2
• Diastereoselective reduction reactions3
• Hydride reduction of the Danishefsky pyranones4
• Asymmetric reductive aldol reaction of enones with a-alkoxy aldehydes5
• Synthesis of alkanols by carbonylation reactions6
Recommended products
推荐使用弯通式隔垫入口接头 Z118206 或直通式隔垫入口接头 Z118141（6mm 内径入口）或直通式隔垫入口接头 Z118192（13mm 内径入口）。
法律信息
Selectride 注册商标 Sigma-Aldrich Co. LLC