二铑催化剂，Rh2(5S-MEPY)4

• 产品号: 424420
• CAS号: 132435-65-5
• 分子式: C24H32N4O12Rh2
• 分子量: 774.34148

产品别名

• 标题: Doyle dirhodium catalyst, Rh2(5S-MEPY)4
• IUPAC标准名: 3,10,16,22-tetramethyl 7λ^3,14λ^3,20λ^3,26λ^3-tetraoxa-2,9,15,21-tetraaza-1,8-dirhodaoctacyclo[6.6.6.6^1,^8.0^1,^8.0^2,^6.0^9,^1^3.0^1^5,^1^9.0^2^1,^2^5]hexacosa-6,13,19,25-tetraene-3,10,16,22-tetracarboxylate
• IUPAC传统名: 3,10,16,22-tetramethyl 7λ^3,14λ^3,20λ^3,26λ^3-tetraoxa-2,9,15,21-tetraaza-1,8-dirhodaoctacyclo[6.6.6.6^1,^8.0^1,^8.0^2,^6.0^9,^1^3.0^1^5,^1^9.0^2^1,^2^5]hexacosa-6,13,19,25-tetraene-3,10,16,22-tetracarboxylate
• 别名: Dirhodium(II)tetrakis[methyl 2-pyrrolidone-5(S)-carboxylate], acetonitrile/2-propanol complex; 二铑四[2-吡咯烷酮-5(S)-羧酸甲酯]，乙腈/2-丙醇络合物

产品登记号

• CAS号: 132435-65-5

产品性质

• Empirical Formula (Hill Notation): C24H32N4O12Rh2
• GHS警示词: Danger
• GHS危险声明: H301-H311-H315-H319-H331-H335
• 欧盟危险性物质标志: 有毒(Toxic) (T)
• 个人保护装置: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• GHS警示性声明: P261-P280-P301 + P310-P305 + P351 + P338-P311
• 危险公开号: 23/24/25-36/37/38-41
• 安全公开号: 22-26-36/37/39-45
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Chiral catalyst used for highly enantioselective intramolecular cyclopropanations, intermolecular addition reactions, and intramolecular carbon-hydrogen insertion reactions. Also employed in the synthesis of lactones and lactams in high diastereo-, regio-, and enantioselectivities. For a recent review, see Aldrichimica Acta 1
Other Notes
For research purposes only-Not for Use in Humans or in Human Clinical Trials.Under Special Agreement with Regis Technologies, Inc.
Legal Information
Sold under license from Regis Technologies, Inc.

详细说明 (简体中文)

Application
用于高效对映选择性分子内环丙烷化、分子间加成反应以及分子内碳氢键插入反应的手性催化剂。也用于在高非对映立体选择性、高区域选择性和高对映选择性条件下合成内酯和内酰胺。最新综述请参阅 Aldrichimica Acta1
Other Notes
仅用于研究目的，禁止用于人体和人体临床试验。遵守与 Regis Technologies，Inc. 的特别协议
Legal Information
经 Regis Technologies，Inc. 授权销售