偶氮二甲酸二乙酯 溶液

• 产品号: 563110
• CAS号: 1972-28-7
• 分子式: C6H10N2O4
• 分子量: 174.1546

产品别名

• 标题: Diethyl azodicarboxylate solution
• IUPAC标准名: N-[(ethoxycarbonyl)imino]ethoxyformamide
• IUPAC传统名: diethyl azodicarboxylate
• 别名: Unifoam AZ-AE 200; Diethoxycarbonyldiazene solution; NSC 679015; Diethyl azodiformate solution; DEAD; 1,2-Ethoxycarbonyl diazene solution; NSC 3474

产品登记号

• MDL号: MFCD00009103
• CAS号: 1972-28-7
• Beilstein号: 908662
• PubChem SID: 24880080

产品性质

• 浓度: 40 wt. % in toluene
• 线性分子式: C2H5OCON=NCOOC2H5
• 沸点: 116-117 °C
• 密度: 0.956 g/mL at 25 °C
• 闪点: 41 °C
• 闪点: 105.8 °F
• 折射率: n20/D 1.4690
• GHS警示词: Danger
• GHS危险声明: H226-H242-H304-H315-H319-H335 + H336-H361d-H373
• 欧盟危险性物质标志: 有害性(Harmful) (Xn)
• 个人保护装置: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS警示性声明: P261-P281-P301 + P310-P305 + P351 + P338-P331
• RID/ADR: UN 3379 3/PG 1
• 危险公开号: 63-5-10-20-36/37/38-48/20-65
• 安全公开号: 26-36/37-62
• 保存温度: 2-8°C
• 联合国危险货物等级: 3
• 联合国危险货物编号: 3379
• 联合国危险货物包装类别(PG): 1
• 德国WGK号: 3

产品详细信息

详细说明 (简体中文)

Application
常用于 Mitsunobo 反应的活化试剂。9
Reactant for preparation of:
• Immunostimulants α-Galactosylceramides1
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases2
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase3
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities4
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes5Reagent for:
• Annulation of N-protected imines6
• α-thiocyanation of enolizable ketones with ammonium thiocyanate7
• Diels-Alder reactions8
General description
DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.
包装
25, 100 g in glass bottle
每 100g 约含 40g DEAD 溶质
每 25g 约含 10g DEAD 溶质
Warning
有毒性、刺激性、易燃

详细说明 (English)

Application
A commonly used activating reagent in Mitsunobo reactions.9
Reactant for preparation of:
• Immunostimulants α-Galactosylceramides1
• Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases2
• Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase3
• Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities4
• Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes5Reagent for:
• Annulation of N-protected imines6
• α-thiocyanation of enolizable ketones with ammonium thiocyanate7
• Diels-Alder reactions8
General description
DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.
Packaging
100g unit contains ca. 40g DEAD solute
25g unit contains ca. 10g DEAD solute
25, 100 g in glass bottle
Warning
Toxic, Irritant, Flammable