三特丁基膦溴化钯

• 产品号: 677728
• CAS号: 185812-86-6
• 分子式: C24H54Br2P2Pd2
• 分子量: 777.281082

产品别名

• 标题: Bromo(tri-tert-butylphosphine)palladium(I) dimer
• IUPAC标准名: bis(bromopalladium); bis(tri-tert-butylphosphane)
• IUPAC传统名: bis(bromopalladium); bis(tri-tert-butylphosphane)
• 别名: Dibromobis(tri-tert-butylphosphine)dipalladium; 三叔丁基溴化膦钯(I); Dibromobis(tri-tert-butylphosphino)dipalladium(I); Pd-113; [Pd(μ-Br)t-Bu3P]2; Palladium(I) tri-tert-butylphosphine bromide, dimer; 二溴双(三叔丁基膦)化钯

产品登记号

• CAS号: 185812-86-6
• PubChem SID: 24885391
• MDL号: MFCD04114019

产品性质

• 线性分子式: [Pd(C4H9)3PBr]2
• GHS警示词: Danger
• GHS危险声明: H250-H261-H314
• 欧盟危险性物质标志: 易燃性(Flammable) (F)
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• GHS警示性声明: P222-P231 + P232-P280-P305 + P351 + P338-P310-P422
• RID/ADR: UN 3393 4.2/PG 1
• 危险公开号: 14-17-34
• 安全公开号: 26-36/37/39-45
• 保存温度: -20°C
• 欧盟补充危害声明: Reacts violently with water.
• 联合国危险货物等级: 4.2
• 联合国危险货物编号: 3393
• 联合国危险货物包装类别(PG): 1
• 德国WGK号: 3

产品详细信息

详细说明 (English)

Application
Catalyst for C-C, C-N, and N-S bond formation.

• Catalyst for γ-arylation of α,β-unsaturated esters from silyl ketene acetals1 (eq. 1)
• Catalyst for carbon -sulfur bond formation2 (eq. 2)
• Catalyst for diastereoselective arylation of 4-substituted cyclohexyl esters3 (eq. 3)
• Catalyst for Suzuki coupling of hindered aryl bromides4 (eq. 4)
• Catalyst for Buchwald-Hartwig amination reaction of aryl halides4 (eq. 5)
• Catalyst for Negishi coupling reaction5 (eq. 6)
Packaging
1 g in glass bottle

详细说明 (简体中文)

Application
Catalyst for C-C, C-N, and N-S bond formation.

• Catalyst for γ-arylation of α,β-unsaturated esters from silyl ketene acetals1 (eq. 1)
• Catalyst for carbon -sulfur bond formation2 (eq. 2)
• Catalyst for diastereoselective arylation of 4-substituted cyclohexyl esters3 (eq. 3)
• Catalyst for Suzuki coupling of hindered aryl bromides4 (eq. 4)
• Catalyst for Buchwald-Hartwig amination reaction of aryl halides4 (eq. 5)
• Catalyst for Negishi coupling reaction5 (eq. 6)
包装
1 g in glass bottle