pentachloro-λ5-phosphane

• ChemBase编号: 89580
• 分子式: Cl5P
• 平均质量: 208.238761
• 单一同位素质量: 205.81802503
• SMILES: P(Cl)(Cl)(Cl)(Cl)Cl
• Canonical SMILES: ClP(Cl)(Cl)(Cl)Cl
• InChI: InChI=1S/Cl5P/c1-6(2,3,4)5
• InChIKey: UHZYTMXLRWXGPK-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: pentachloro-λ^5-phosphane; pentachloro-$l^{5}-phosphane
• IUPAC传统名: pentachloro-λ^5-phosphane; phosphorus pentachloride
• 别名: 氯化磷(V); 五氯化磷; 聚合物键合型氯化磷(V); 聚合物键合型五氯化磷; 氯化磷(V); Phosphorus pentachloride; Phosphorus pentachloride; Phosphorus(V) chloride, polymer-bound; Phosphorus pentachloride, polymer-bound; Pentachlorophosphorane; Phosphorus(V) chloride; Phosphorus pentachloride 98+%; Phosphorus(V) chloride

登记号

• CAS号: 10026-13-8
• EC号: 233-060-3
• MDL号: MFCD00011439
• 默克索引号: 147351
• PubChem SID: 162076455; 24849700; 24883291
• PubChem CID: 24819
• 维基百科标题: Phosphorus_pentachloride

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 3.4725
• LogD (pH = 7.4): 3.4725
• Log P: 3.4725
• 摩尔折射率: 35.8815 cm^3
• 极化性: 14.072733 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: decomposition; (exothermic) in water; Soluble in carbon disulfide and carbon tetrachloride; soluble in CS₂, chlorocarbons, benzene
• 外观: colourless crystals; macroporous; Solid
• 熔点: 162°C subl.; 166.8 °C, 440.0 K, 332.2 °F; 179-181 °C (subl.)(lit.); 179-181(subl.)°C
• 沸点: 160.5°C (sublimation)
• 闪点: Non-flammable
• 密度: 2.1 g/cm^3; 2.114
• 蒸汽压: <1 mmHg ( 20 °C)

安全信息

• 保存注意事项: Moisture Sensitive; Very Toxic/Corrosive/Harmful/Moisture Sensitive/Store under Argon
• RTECS编号: TB6125000
• 欧盟危险性物质标志: 剧毒(Highly toxic) (T+)
• 联合国危险货物编号: 1806; UN1806
• 德国WGK号: 1; 3
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 14-22-26-29-34-48/20; 14-22-26-34-48/20; R14, R22, R26, R34, R48/20
• 安全公开号: 7/8-26-36/37/39-45; S1/2, S7/8, S26, S36/37/39, S45
• TSCA收录: 是
• 欧盟危险品索引: 015-008-00-X
• GHS危险品标识: GHS05; GHS06; GHS08
• GHS警示词: Danger
• NFPA704:
  

  0

  3

  2

  W
• 半数致死量: 660 mg/kg
• GHS危险声明: H302-H314-H330-H373; H330-H302-H314-H373
• GHS警示性声明: P260-P280-P284-P305 + P351 + P338-P310; P260-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501A
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• RID/ADR: UN 1806 8/PG 2
• 欧盟补充危害声明: Reacts violently with water.
• 保存温度: 2-8°C

产品相关信息

• 纯度: 95%; 98%; 99.998% (metals basis)
• 级别: CP; reagent grade
• 颗粒大小: 16-50 mesh
• 标签扩展内容: 1.0-1.5 mmol/g loading
• 线性分子式: PCl5

详细说明

Sigma Aldrich - 643726

包装
25 g in glass bottle

Sigma Aldrich - 157775

包装
1 kg in glass bottle
5, 100 g in glass bottle