dichloropalladium; bis(triphenylphosphane)

• ChemBase编号: 64371
• 分子式: C36H30Cl2P2Pd
• 平均质量: 701.896922
• 单一同位素质量: 700.02346558
• SMILES: [Pd](Cl)Cl.c1(P(c2ccccc2)c2ccccc2)ccccc1.c1(P(c2ccccc2)c2ccccc2)ccccc1
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.Cl[Pd]Cl
• InChI: InChI=1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChIKey: YNHIGQDRGKUECZ-UHFFFAOYSA-L

名称和登记号

名称

• IUPAC标准名: dichloropalladium; bis(triphenylphosphane)
• IUPAC传统名: palladium chloride; bis(triphenylphosphine)
• 别名: 三苯基膦氯化钯; 二氯二(三苯基膦)钯(II); 双(三苯基膦)二氯化钯(II); ChemDose™ 双三苯基膦二氯化钯(II)片剂; PdCl2(PPh3)2 浸渍片剂; 三苯基膦氯化钯(II)浸渍片剂; 二氯二(三苯基膦)钯(II) 浸渍片剂; 双三苯基膦二氯化钯(II) 浸渍片剂; 双三苯基膦二氯化钯(II)，ChemDose™ 片剂; Bis(triphenylphosphine)palladium(II) chloride; Dichlorobis(triphenylphosphine)palladium(II); Palladium(II)bis(triphenylphosphine) dichloride; Bis(triphenylphosphine)palladium(II) dichloride; PdCl2(PPh3)2; Bis(triphenylphosphine)palladium(II) dichloride impregnated tablets; ChemDose™, Bis(triphenylphosphine)palladium(II) dichloride tablets; Dichlorobis(triphenylphosphine)palladium(II) impregnated tablets; Palladium(II) bis(triphenylphosphine) dichloride impregnated tablets; PdCl2(PPh3)2 impregnated tablets; Bis(triphenylphosphine)palladium(II) dichloride, ChemDose™ tablets; Bis(triphenylphosphine)palladium(II) dichloride

登记号

• CAS号: 13965-03-2
• EC号: 237-744-2
• MDL号: MFCD00009593
• Beilstein号: 4935975
• PubChem SID: 162030110; 24885842; 24865821; 24849233; 24852524
• PubChem CID: 6102075

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• 摩尔折射率: 81.6229 cm^3
• 极化性: 32.34495 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 6
• 里宾斯基五规则: false

分子性质

理化性质

• 熔点: 300°C

安全信息

• 保存注意事项: IRRITANT; Irritant/Store under Argon/Hygroscopic/Moisture Sensitive
• 德国WGK号: 3
• TSCA收录: false
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 欧盟补充危害声明: May form explosive peroxides.

产品相关信息

• 纯度: ≥98.0% (Pd); ≥99% trace metals basis; ≥99.99% trace metals basis; 98%
• 级别: purum
• 基质: Magnesium aluminometasilicate base material
• 线性分子式: [(C6H5)3P]2PdCl2

详细说明

Sigma Aldrich - 741248

包装
1, 5, 25 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Sigma Aldrich - 412740

Application
Catalyst for C-C coupling reaction via Negishi coupling, Suzuki coupling, Sonogashira coupling, and Heck coupling reaction.
一锅法合成呋喃喹啉，通过钯催化 Sonogashira 偶联反应以及后续的铜(I) 催化闭环反应。芳基炔与 2-溴噻唑和 2-溴噻吩的 Sonogashira 偶联反应的催化剂。
交叉偶联反应催化剂。
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
包装
1, 5 g in glass bottle
25 g in poly bottle
250 mg in glass bottle

Sigma Aldrich - 685607

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
法律信息
ChemDose 商标 Reaxa Ltd.

Sigma Aldrich - 208671

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
碘代-α-β-不饱和酯经钯催化偶联可生成四取代烯烃1
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
包装
1, 5, 25, 100 g in glass bottle

Sigma Aldrich - 15253

Other Notes
综述1
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions