tris(triphenyl-λ5-phosphanyl)rhodiumylium chloride

• ChemBase编号: 179298
• 分子式: C54H45ClP3Rh
• 平均质量: 925.214883
• 单一同位素质量: 924.14776801
• SMILES: P([Rh+](P(c1ccccc1)(c1ccccc1)c1ccccc1)P(c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]
• Canonical SMILES: c1ccc(cc1)P([Rh+](P(c1ccccc1)(c1ccccc1)c1ccccc1)P(c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-]
• InChI: InChI=1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;-2/p+2
• InChIKey: UTODFRQBVUVYOB-UHFFFAOYSA-P

名称和登记号

名称

• IUPAC标准名: tris(triphenyl-λ^5-phosphanyl)rhodiumylium chloride
• IUPAC传统名: tris(triphenyl-λ^5-phosphanyl)rhodiumylium chloride
• 别名: Chlorotris(triphenylphosphine)rhodium; Chlorotris(triphenylphosphine)rhodium(I); NSC 124140; Rhodium tris(triphenylphosphine) chloride; Tris(triphenylphosphine)chlororhodium; Tris(triphenylphosphine)chlororhodium(I); Tris(triphenylphosphine)rhodium(I) Chloride; Wilkinson's Catalyst; Wilkinson's Complex; Tris(triphenylphosphine)rhodium(I) Chloride

登记号

• CAS号: 14694-95-2
• PubChem SID: 164235208
• PubChem CID: 71752856

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 14.3418
• LogD (pH = 7.4): 14.3418
• Log P: 14.3418
• 摩尔折射率: 247.2687 cm^3
• 极化性: 102.005936 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 12
• 里宾斯基五规则: false

分子性质

理化性质

• 溶解度: Chloroform
• 外观: Dark Red Solid

安全信息

• 保存条件: Refrigerator, Under Inert Atmosphere

详细说明

Toronto Research Chemicals - T886465

Tris(triphenylphosphine)rhodium Chloride is also known as Wilkinson's catalyst and is commonly used to catalyze the hydrogenation of alkenes. Tris(triphenylphosphine)rhodium(I) Chloride is also used in the catalytic hydroboration of alkenes with catecholb

参考文献

• Evans, D.A. et al.: J. Am. Chem. Soc., 110, 6917 (1988)
• Ojima, I. et al.: Tetrahedron Lett., 13, 5035 (1988)
• Birch, A.J. et al.: Org. React., 24 (1988)