oxo[(oxonickelio)oxy]nickel

• ChemBase编号: 151985
• 分子式: Ni2O3
• 平均质量: 165.385
• 单一同位素质量: 163.85542966
• SMILES: O=[Ni]O[Ni]=O
• Canonical SMILES: O=[Ni]O[Ni]=O
• InChI: InChI=1S/2Ni.3O
• InChIKey: PZFKDUMHDHEBLD-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: oxo[(oxonickelio)oxy]nickel
• IUPAC传统名: oxo[(oxonickelio)oxy]nickel
• 别名: 过氧化镍; Nickel dioxide; Nickel oxide; Nickel peroxide

登记号

• CAS号: 12035-36-8
• EC号: 234-823-3
• MDL号: MFCD00011143
• PubChem SID: 24886379; 162246131
• PubChem CID: 10855842

理论计算性质

• 质子受体: 2
• 质子供体: 0
• LogD (pH = 5.5): -1.9316
• LogD (pH = 7.4): -1.9316
• Log P: -1.9316
• 摩尔折射率: 4.236 cm^3
• 极化性: 9.124384 Å^3
• 极化表面积: 43.37 Å^2
• 可自由旋转的化学键: 2
• 里宾斯基五规则: true

分子性质

安全信息

• 欧盟危险性物质标志: 有毒(Toxic) (T)
• 联合国危险货物编号: 1479
• 德国WGK号: 1
• 联合国危险货物等级: 5.1
• 联合国危险货物包装类别(PG): 2
• 危险公开号: 49-43-48/23-53
• 安全公开号: 53-45-61
• GHS危险品标识: GHS07; GHS08
• GHS警示词: Danger
• GHS危险声明: H317-H350i-H372-H413
• GHS警示性声明: P201-P280-P308 + P313
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1479 5.1/PG 2

产品相关信息

• 纯度: ~30% active peroxide basis
• 级别: oxidizing agent; technical
• Empirical Formula (Hill Notation): NiO2

详细说明

Sigma Aldrich - 72262

Other Notes
醇转化为酸以及腙转化为重氮烷的氧化剂6,7
包装
5 g in poly bottle
Application
Catalyst for:
• One-dimensional oxide-metal hybrid structures and site-specific enhanced reactivity for CO oxidation1
• Microwave induced catalytic degradation of crystal violet2Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters3Reagent:
• For solvent-free oxidation of alcohols†
• For chemoselective oxidation of organic compounds using inductive heating4
• To improve the synthesis of methoxy cephalosporin′s intermediate5