dibromopalladium; bis(triphenylphosphane)

• ChemBase编号: 151885
• 分子式: C36H30Br2P2Pd
• 平均质量: 790.798922
• 单一同位素质量: 787.92243422
• SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.Br[Pd]Br
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.Br[Pd]Br
• InChI: InChI=1S/2C18H15P.2BrH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChIKey: MCSDDEAMPOYJJI-UHFFFAOYSA-L

名称和登记号

名称

• IUPAC标准名: dibromopalladium; bis(triphenylphosphane)
• IUPAC传统名: dibromopalladium; bis(triphenylphosphine)
• 别名: 反式双(三苯基膦)二氯溴钯(II); trans-Dibromobis(triphenylphosphine)palladium(II)

登记号

• CAS号: 22180-53-6
• MDL号: MFCD00134175
• PubChem SID: 24862152; 162246031
• PubChem CID: 11104744

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• 摩尔折射率: 81.6229 cm^3
• 极化性: 32.34495 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 6
• 里宾斯基五规则: false

分子性质

安全信息

• 德国WGK号: 3

产品相关信息

• 纯度: 95%
• 线性分子式: [(C6H5)3P]2PdBr2

详细说明

Sigma Aldrich - 360163

包装
1, 5 g in glass bottle
Application
Catalyst for:
• Equilibrium palladation of alkanes and arenes and functionalization of hydrocarbons1Reactant for:
• Homocoupling reactions induced by P-C reductive elimination2
• Preparation of palladium imidazolylidene complexes via Suzuki coupling reactions3