triphenylmethanamine

• ChemBase编号: 151406
• 分子式: C19H17N
• 平均质量: 259.34498
• 单一同位素质量: 259.13609955
• SMILES: c1ccc(cc1)C(c1ccccc1)(c1ccccc1)N
• Canonical SMILES: NC(c1ccccc1)(c1ccccc1)c1ccccc1
• InChI: InChI=1S/C19H17N/c20-19(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H,20H2
• InChIKey: BZVJOYBTLHNRDW-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: triphenylmethanamine
• IUPAC传统名: triphenylmethanamine
• 别名: 三苯基甲胺; 三苯甲胺; 三甲苯基胺; Tritylamine; Triphenylmethylamine; Triphenylmethylamine; Tritylamine; triphenylmethanamine; α,α-Diphenylbenzenemethanamine; Aminotriphenylmethane; NSC 1154; Triphenylmethanamine; Triphenylmethylamine

登记号

• CAS号: 5824-40-8
• MDL号: MFCD00008047
• Beilstein号: 2113674
• PubChem SID: 162245560; 24859510; 24889784
• PubChem CID: 138598

理论计算性质

• 质子受体: 1
• 质子供体: 1
• LogD (pH = 5.5): 1.767307
• LogD (pH = 7.4): 3.3120546
• Log P: 4.531496
• 摩尔折射率: 84.969 cm^3
• 极化性: 33.034218 Å^3
• 极化表面积: 26.02 Å^2
• 可自由旋转的化学键: 3
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: Chloroform; Methanol
• 外观: Off-White Solid
• 熔点: 100-104°C; 102-104 °C; 102-104 °C(lit.); 102-104°C
• 沸点: 223 °C/14 mmHg(lit.); 223°C/14mm
• 疏水性(logP): 3.88

安全信息

• 保存条件: Refrigerator
• 保存注意事项: Air Sensitive
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 德国WGK号: 3
• 危险公开号: 36/37/38
• 安全公开号: 26-36; 26-37
• TSCA收录: 否
• GHS危险品标识: GHS07
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• GHS警示性声明: P261-P305 + P351 + P338; P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves

产品相关信息

• 纯度: ≥98.0% (NT); 95%; 98%; 99%
• 级别: purum
• 线性分子式: (C6H5)3CNH2

详细说明

Sigma Aldrich - 325430

包装
5 g in glass bottle

Sigma Aldrich - 93075

Other Notes
有机合成中氨的等价物；通过 N-三苯甲基亚胺合成 1-(三苯甲基氨基)烷基膦酸酯1

Toronto Research Chemicals - T808960

Triphenylmethylamine is a trityl derivative that is structurally related to Clotrimazole (C587400). Triphenylmethylamine is used in the preparation of trityl-cysteine analogs as inhibitors of human mitotic kinesin. Triphenylmethylamine is also used as a f

参考文献

• Gnedin, E.V. et al.: Plast. Mas., 4, 79 (1989)
• DeBonis, S. J. Med. Chem., 51, 1115 (1989)
• Matsuura, Y. et al.: Biochem. Pharmacol., 41, 1949 (1989)
• Protected form of ammonia: the trityl group is removable by strong acid. For use in the synthesis of 1-aminoalkanephosphonic esters or acids, see: Synthesis, 370 (1988):