boranylidenetrimethylamine

• ChemBase编号: 148773
• 分子式: C3H11BN
• 平均质量: 71.93714
• 单一同位素质量: 72.09845476
• SMILES: [BH2-][N+](C)(C)C
• Canonical SMILES: [BH2-][N+](C)(C)C
• InChI: InChI=1S/C3H12BN/c1-5(2,3)4/h1-4H3
• InChIKey: KQVSXUGMDCAISO-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: boranylidenetrimethylamine
• IUPAC传统名: boranylidenetrimethylamine
• 别名: 三甲胺硼烷; 硼烷三甲胺络合物; NSC 10220; NSC 145941; NSC 53323; Trihydro(trimethylamine)boron; Trimethylamine borane; Borane trimethylamine complex

登记号

• CAS号: 75-22-9
• EC号: 200-850-4
• MDL号: MFCD00012420
• Beilstein号: 3905060
• PubChem SID: 162242948; 24849578; 24850786
• PubChem CID: 6327651

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): -4.7170744
• LogD (pH = 7.4): -4.7170744
• Log P: -4.7170744
• 摩尔折射率: 22.9901 cm^3
• 极化性: 10.122457 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 熔点: 92-94 °C(lit.); 93-95 °C
• 沸点: 172 °C(lit.)

安全信息

• 欧盟危险性物质标志: 易燃性(Flammable) (F); 刺激性(Irritant) (Xi); 有害性(Harmful) (Xn)
• 联合国危险货物编号: 1325
• 德国WGK号: 3
• 联合国危险货物等级: 4.1
• 联合国危险货物包装类别(PG): 2
• 危险公开号: 11-36/37/38
• 安全公开号: 14-16-26-36; 16-26-36
• GHS危险品标识: GHS02; GHS07
• GHS警示词: Danger
• GHS危险声明: H228-H315-H319-H335
• GHS警示性声明: P210-P261-P305 + P351 + P338
• RID/ADR: UN 1325 4.1/PG 2

产品相关信息

• 纯度: ≥95.0% (T); 97%
• 级别: purum
• 线性分子式: (CH3)3N · BH3

详细说明

Sigma Aldrich - 178985

包装
5, 25, 100 g in glass bottle
Application
Reducing agent for the preparation of plate-type palladium-zinc oxide catalyst1Reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents2Catalyst for:
• Regioselective reductive opening of benzylidene acetal glycosides3
• Polarity reversal4Used to study
• Electrodeposition condition effects on magnetism of cobalt-iron magnetic films5
• Boron-nitrogen bond dissociation energies and physiological activities of boronated compounds6
稳定、易处理的硼烷源，用于酮和席夫碱的还原反应以及烯烃的硼氢化反应。

Sigma Aldrich - 15591

Other Notes
综述7
Application
Reducing agent for the preparation of plate-type palladium-zinc oxide catalyst1Reagent for chemical vapor generation and spectrometry determination of elements using amineboranes and cyanotrihydroborate(III) reagents2Catalyst for:
• Regioselective reductive opening of benzylidene acetal glycosides3
• Polarity reversal4Used to study
• Electrodeposition condition effects on magnetism of cobalt-iron magnetic films5
• Boron-nitrogen bond dissociation energies and physiological activities of boronated compounds6