hexafluoro-λ5-phosphanuide; triphenylmethylium

• ChemBase编号: 147421
• 分子式: C19H15F6P
• 平均质量: 388.2865802
• 单一同位素质量: 388.08155643
• SMILES: c1ccc(cc1)[C+](c1ccccc1)c1ccccc1.F[P-](F)(F)(F)(F)F
• Canonical SMILES: c1ccc(cc1)[C+](c1ccccc1)c1ccccc1.F[P-](F)(F)(F)(F)F
• InChI: InChI=1S/C19H15.F6P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7(2,3,4,5)6/h1-15H;/q+1;-1
• InChIKey: IBTFOFOFRZKIJU-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: hexafluoro-λ^5-phosphanuide; triphenylmethylium
• IUPAC传统名: triphenylmethylium hexafluorophosphate
• 别名: 三苯基六氟磷酸碳; 三苯基六氟磷酸碳; NSC 176018; Triphenylcarbonium hexafluorophosphate; Triphenylmethyl hexafluorophosphate; Trityl hexafluorophosphate; Tritylium hexafluorophosphate; Triphenylcarbenium hexafluorophosphate; Tritylium hexafluorophosphate

登记号

• CAS号: 437-17-2
• EC号: 207-112-0
• MDL号: MFCD00013121
• Beilstein号: 4344297
• PubChem SID: 24850084; 162241609; 24889889
• PubChem CID: 2723954

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 2.030707
• LogD (pH = 7.4): 2.030707
• Log P: 2.030707
• 摩尔折射率: 79.5869 cm^3
• 极化性: 31.464106 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 3
• 里宾斯基五规则: true

分子性质

理化性质

• 熔点: ~150 °C (dec.)(lit.); ca 160°C dec.

安全信息

• 保存注意事项: Moisture Sensitive
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C)
• 联合国危险货物编号: 3261; UN3261
• 德国WGK号: 3
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 34
• 安全公开号: 26-36/37/39-45
• TSCA收录: 是
• GHS危险品标识: GHS05
• GHS警示词: Danger
• GHS危险声明: H314; H314-H318
• GHS警示性声明: P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P310; P280-P305 + P351 + P338-P310
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3261 8/PG 2
• 保存温度: 2-8°C

产品相关信息

• 纯度: ≥97.0% (CHN); 98%
• 级别: purum
• 线性分子式: (C6H5)3C(PF6)

详细说明

Sigma Aldrich - 164569

包装
10 g in poly bottle
Application
Reactant of reagent involved in:
• Si-H and Si-Si bond activeation at Pt of neutral and cationic silyl Pt bisphosphine complexes1
• Investigations of interactions with chromium acetylacetonate nitride mononuclear complexes2
• Synthesis of "push-pull" tropylium-fused aminoporphyrazine3
• Preparation of cycloheptatrienyl and tropylium calix[4]arenes4
• Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst5
• Double ring-opening polyaddition of spiro orthoesters6

Sigma Aldrich - 93456

Application
Reactant of reagent involved in:
• Si-H and Si-Si bond activeation at Pt of neutral and cationic silyl Pt bisphosphine complexes1
• Investigations of interactions with chromium acetylacetonate nitride mononuclear complexes2
• Synthesis of "push-pull" tropylium-fused aminoporphyrazine3
• Preparation of cycloheptatrienyl and tropylium calix[4]arenes4
• Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst5
• Double ring-opening polyaddition of spiro orthoesters6