tetramethylazanium boranuide

• ChemBase编号: 146075
• 分子式: C4H15BN
• 平均质量: 87.9796
• 单一同位素质量: 88.12975489
• SMILES: [BH3-].C[N+](C)(C)C
• Canonical SMILES: C[N+](C)(C)C.[BH3-]
• InChI: InChI=1S/C4H12N.BH4/c1-5(2,3)4;/h1-4H3;1H4/q+1;-1
• InChIKey: LSSMEJCYZMCNIN-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: tetramethylazanium boranuide
• IUPAC传统名: tetramethylammonium boranuide
• 别名: 四甲基硼氢化铵; (聚苯乙烯基甲基)三甲胺硼氢化物; Amberlite® IRA-400 负载的硼氢化物; 聚合物负载的硼氢化物; (Polystyrylmethyl)trimethylammonium borohydride; Borohydride on Amberlite® IRA-400; NSC 164901; TMAB; Tetramethylammonium borohydride; Tetramethylammonium tetrahydridoborate; Borohydride, polymer-supported

登记号

• CAS号: 16883-45-7
• EC号: 240-917-5
• MDL号: MFCD00011778
• Beilstein号: 3684968
• PubChem SID: 24858811; 162240274; 24859390; 24862127
• PubChem CID: 6328186

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): -3.9721673
• LogD (pH = 7.4): -3.9721673
• Log P: -3.9721673
• 摩尔折射率: 35.9017 cm^3
• 极化性: 9.572162 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 熔点: >250°C dec.
• 密度: 0.813

安全信息

• 保存注意事项: Moisture Sensitive
• RTECS编号: BS8310000
• 欧盟危险性物质标志: 易燃性(Flammable) (F); 有毒(Toxic) (T); 刺激性(Irritant) (Xi)
• 联合国危险货物编号: 2925; 3134; UN3131
• 德国WGK号: 3
• 联合国危险货物等级: 4.1; 4.3
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 11-36/37/38; 15-24/25-34; 15-25-36/38; 36/37/38
• 安全公开号: 16-26; 26-36; 26-36/37/39-43-45; 7/8-26-36/37/39-43-45
• TSCA收录: 是
• GHS危险品标识: GHS02; GHS05; GHS06; GHS07
• GHS警示词: Danger; Warning
• GHS危险声明: H261-H301-H311-H314-H318; H261-H301-H315-H319; H315-H319-H335
• GHS警示性声明: P231 + P232-P301 + P310-P305 + P351 + P338-P422; P261-P305 + P351 + P338; P280-P303+P361+P353-P305+P351+P338-P310-P370+P378I-P402+P404
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 2925 4.1/PG 2; UN 3134 4.3/PG 2
• 保存温度: 2-8°C

产品相关信息

• 纯度: ≥90% (gas-volumetric); 95%
• 级别: technical
• 颗粒大小: 20-50 mesh
• 标签扩展内容: ~2.5 mmol/g loading
• 线性分子式: (CH3)4N(BH4)

详细说明

Sigma Aldrich - 359947

包装
10, 50 g in glass bottle
Application
比对应的碱金属硼氢化物具有更高选择性的还原剂。1

Sigma Aldrich - 310689

包装
10, 50 g in glass bottle
Application
Reactant for:
• Preparation of iridium tetrahydride complexes bearing a tridentate pincer-type bis(phosphino)silyl ligand1
• Reduction reactions (reducing agent)2

Sigma Aldrich - 328642

包装
25, 100 g in glass bottle
Application
用于 α,β-不饱和醛和酮选择性还原生成烯丙醇的试剂。1
法律信息
Amberlite 注册商标 The Dow Chemical Company or an affiliated company of Dow

Sigma Aldrich - 87700

Application
Reactant for:
• Preparation of iridium tetrahydride complexes bearing a tridentate pincer-type bis(phosphino)silyl ligand1
• Reduction reactions (reducing agent)2