[(diethylamino)(phenyl)phosphanyl]diethylamine

• ChemBase编号: 144784
• 分子式: C14H25N2P
• 平均质量: 252.335461
• 单一同位素质量: 252.17553544
• SMILES: CCN(CC)P(c1ccccc1)N(CC)CC
• Canonical SMILES: CCN(P(c1ccccc1)N(CC)CC)CC
• InChI: InChI=1S/C14H25N2P/c1-5-15(6-2)17(16(7-3)8-4)14-12-10-9-11-13-14/h9-13H,5-8H2,1-4H3
• InChIKey: HTIVDCMRYKVNJC-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: [(diethylamino)(phenyl)phosphanyl]diethylamine
• IUPAC传统名: [(diethylamino)(phenyl)phosphanyl]diethylamine
• 别名: 双(二乙基氨基)苯膦; N,N,N′N′-Tetraethylphenylphosphonous diamide; NSC 244337; Phenylphosphonous tetraethyldiamide; Bis(diethylamino)phenylphosphine

登记号

• CAS号: 1636-14-2
• MDL号: MFCD01634466
• PubChem SID: 24879428; 162238996
• PubChem CID: 137129

理论计算性质

• 质子受体: 2
• 质子供体: 0
• LogD (pH = 5.5): 1.4778575
• LogD (pH = 7.4): 2.1750174
• Log P: 2.8486
• 摩尔折射率: 77.4555 cm^3
• 极化性: 30.873552 Å^3
• 极化表面积: 6.48 Å^2
• 可自由旋转的化学键: 7
• 里宾斯基五规则: true

分子性质

理化性质

• 沸点: 80 °C/0.005 mmHg(lit.)
• 闪点: 106 °C; 222.8 °F
• 密度: 0.971 g/mL at 25 °C(lit.)

安全信息

• 德国WGK号: 3
• 个人保护装置: Eyeshields, Gloves

产品相关信息

• 纯度: 97%
• 线性分子式: C6H5P(N(CH2CH3)2)2

详细说明

Sigma Aldrich - 554707

包装
5 g in glass bottle
Application

• Electron-withdrawing cocatalyst in rhodium catalyzed hydroformylation reactions1
• Ligand precatalyst for Heck coupling reactions2Reactant for:
• Preparation of palladium chiral P-N ligand complexes for regio- and stereo-selective dimerization reactions3
• Preparation of palladium tautomeric ferrocenylphosphinites as catalysts for Suzuki-Miyaura coupling4
• Trimethylsilyl halide-promoted Michaelis-Arbuzov rearrangement of phosphinites and phosphites5