λ1-rhodium(1+) ion bis(cycloocta-1,5-diene) hexafluorostibanuide

• ChemBase编号: 142560
• 分子式: C16H24F6RhSb
• 平均质量: 555.0176792
• 单一同位素质量: 553.98753909
• SMILES: C1C=CCCC=CC1.C1C=CCCC=CC1.F[Sb-](F)(F)(F)(F)F.[Rh+]
• Canonical SMILES: C1CC=CCCC=C1.C1CC=CCCC=C1.F[Sb-](F)(F)(F)(F)F.[Rh+]
• InChI: InChI=1S/2C8H12.6FH.Rh.Sb/c2*1-2-4-6-8-7-5-3-1;;;;;;;;/h2*1-2,7-8H,3-6H2;6*1H;;/q;;;;;;;;+1;+5/p-6
• InChIKey: BROZUPPJWNODCU-UHFFFAOYSA-H

名称和登记号

名称

• IUPAC标准名: λ^1-rhodium(1+) ion bis(cycloocta-1,5-diene) hexafluorostibanuide; λ^1-rhodium(1+) ion bis((1Z,5Z)-cycloocta-1,5-diene) hexafluorostibanuide
• IUPAC传统名: λ^1-rhodium(1+) ion bis(1,5-cyclooctadiene) hexafluorostibanuide; λ^1-rhodium(1+) ion bis(1,5-cyclooctadiene, (Z,Z)-) hexafluorostibanuide
• 别名: 双(1,5-环辛二烯)铑(I)六氟化锑盐; Bis(1,5-cyclooctadiene)rhodium(I) hexafluoroantimonate

登记号

• CAS号: 130296-28-5
• MDL号: MFCD11113031
• PubChem SID: 162236787
• PubChem CID: 16688726

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 2.832706
• LogD (pH = 7.4): 2.832706
• Log P: 2.832706
• 摩尔折射率: 39.0412 cm^3
• 极化性: 14.319889 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: false

分子性质

理化性质

• 外观: Crystalline powder
• 熔点: 58-60 °C

安全信息

• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N); X
• 联合国危险货物编号: UN3077
• 德国WGK号: 3
• 联合国危险货物等级: 9
• 联合国危险货物包装类别(PG): III
• 危险公开号: 20/22-51/53
• 安全公开号: 61
• TSCA收录: 否
• GHS危险品标识: GHS07; GHS09
• GHS危险声明: H302-H332-H411-H401
• GHS警示性声明: P261-P273-P304+P340-P301+P312-P312-P501A
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• 保存温度: -20°C

产品相关信息

• 纯度: 97%
• Empirical Formula (Hill Notation): C16H24F6RhSb

详细说明

Sigma Aldrich - 701629

包装
1 g in glass bottle
250 mg in glass bottle
Application
Catalyst for:
• [3+2] Cycloaddition1
• Preparation of diastereomeric chiral phosphorus mon- and bidentate diamidophosphite ligands based on dianydromannitol and their use in asymmetric metallocomplex catalysis2
• C-C bond-forming hydrogenation3,4