[1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]diphenylphosphane

• ChemBase编号: 141629
• 分子式: C33H25OP
• 平均质量: 468.524761
• 单一同位素质量: 468.16430205
• SMILES: COc1ccc2ccccc2c1c1c2ccccc2ccc1P(c1ccccc1)c1ccccc1
• Canonical SMILES: COc1ccc2c(c1c1c(ccc3c1cccc3)P(c1ccccc1)c1ccccc1)cccc2
• InChI: InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3
• InChIKey: KRWTWSSMURUMDE-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]diphenylphosphane
• IUPAC传统名: [1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]diphenylphosphane
• 别名: (R)-(+)-2-(二苯基膦)-2′-甲氧基-1,1′-联萘; (R)-(+)-2-(Diphenylphosphino)-2′-methoxy-1,1′-binaphthyl; R-MOP; (S)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine; (R)-(2'-Methoxy-[1,1'-binaphthalen]-2-yl)diphenylphosphine

登记号

• CAS号: 145964-33-6; 134484-36-9
• MDL号: MFCD00269686
• PubChem SID: 162235863
• PubChem CID: 4190002

理论计算性质

• 质子受体: 1
• 质子供体: 0
• LogD (pH = 5.5): 8.5427
• LogD (pH = 7.4): 8.5427
• Log P: 8.5427
• 摩尔折射率: 146.1227 cm^3
• 极化性: 61.167408 Å^3
• 极化表面积: 9.23 Å^2
• 可自由旋转的化学键: 4
• 里宾斯基五规则: false

分子性质

理化性质

• 比旋光度: [α]20/D +94°, c = 0.5 in chloroform

安全信息

• 德国WGK号: 3
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

产品相关信息

• 纯度: ≥94%; 97%; 98%
• Empirical Formula (Hill Notation): C33H25OP

详细说明

Sigma Aldrich - 693537

Application
Takasago Ligands and Complexes for Asymmetric ReactionsLigand used in palladium-catalyzed asymmetric hydrosilylation of olefins1,2, palladium-catalyzed reduction of allylic esters3, rhodium-catalyzed asymmetric addition reactions4,5, and asymmetric amination reactions catalyzed by copper(I) complexes6.
包装
50, 100 mg in glass bottle
Legal Information
与 Takasago 联合销售，仅供研究之用。US5231202