(acetyloxy)palladio acetate

• ChemBase编号: 140453
• 分子式: C4H6O4Pd
• 平均质量: 224.50804
• 单一同位素质量: 223.93009467
• SMILES: CC(=O)O[Pd]OC(=O)C
• Canonical SMILES: CC(=O)O[Pd]OC(=O)C
• InChI: InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
• InChIKey: YJVFFLUZDVXJQI-UHFFFAOYSA-L

名称和登记号

名称

• IUPAC标准名: (acetyloxy)palladio acetate
• IUPAC传统名: (acetyloxy)palladio acetate
• 别名: 乙酸钯(II); ChemDose™，乙酸钯(II) 片剂; Pd(OAc)2 浸渍片剂; 乙酸钯(II) 浸渍片剂; 乙酸钯(II)，ChemDose™ 片剂; 重结晶乙酸钯(II); Pd(OAc)2; Palladium(II) acetate; ChemDose™, Palladium(II) acetate tablets; Palladium(II) acetate impregnated tablets; Pd(OAc)2 impregnated tablets; Palladium(II) acetate, ChemDose™ tablets; Palladium(II) acetate, recrystallized

登记号

• CAS号: 3375-31-3
• EC号: 222-164-4
• MDL号: MFCD00012453
• Beilstein号: 6086766
• PubChem SID: 162234697; 24852356; 24863696; 24874166; 24885841
• PubChem CID: 4144353

理论计算性质

• 质子受体: 2
• 质子供体: 0
• LogD (pH = 5.5): -0.1134
• LogD (pH = 7.4): -0.1134
• Log P: -0.1134
• 摩尔折射率: 23.4322 cm^3
• 极化性: 14.697714 Å^3
• 极化表面积: 52.6 Å^2
• 可自由旋转的化学键: 4
• 里宾斯基五规则: true

分子性质

理化性质

• 外观: powder
• 熔点: 216.3-223.7 °C (dec.); 227-231 °C

安全信息

• RTECS编号: AJ1900000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 刺激性(Irritant) (Xi); 有害性(Harmful) (Xn)
• 德国WGK号: 2; 3
• 危险公开号: 35; 40-41; 41
• 安全公开号: 26-36/37/39; 26-36/37/39-45; 26-39
• GHS危险品标识: GHS05; GHS08
• GHS警示词: Danger
• GHS危险声明: H314-H361d; H318; H318-H351
• GHS警示性声明: P280-P305 + P351 + P338; P280-P305 + P351 + P338-P310
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves

产品相关信息

• 纯度: ≥99.9% trace metals basis; 47% Pd basis; 97%; 98%; 99.98% trace metals basis
• 级别: purum; reagent grade
• 基质: Magnesium aluminometasilicate base material; Magnesium aluminometasilicate particle platform
• 线性分子式: Pd(OCOCH3)2

详细说明

Sigma Aldrich - 720070

包装
1 g in glass bottle

Sigma Aldrich - 379875

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
一种非卤化钯(II) 复合物。已被用作偶合反应的催化剂，以及1作为前体用于制备非均相催化的含钯材料。2,3
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
包装
1, 5 g in poly bottle

Sigma Aldrich - 520764

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
包装
1, 5, 25 g in glass bottle
Application

• Catalyst for formation of allylic acetates (eq. 1)
• Catalyst for hydroselenation of triple bonds (eq. 2)
• Catalyst for the Heck arylation of alkenes (eq. 3)
• Catalyst for cyclocarbonylation (eq. 4)
• Catalyst for Buchwald-Hartwig amination reaction (eq. 5)
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Sigma Aldrich - 683124

包装
5 g in glass bottle
500 mg in glass bottle
Legal Information
Umicore 产品
Application
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Sigma Aldrich - 684929

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
包装
10, 100 tablets in glass bottle
Application
ChemDose: Convenient Dosing of Catalysts and Reagents
法律信息
ChemDose 商标 Reaxa Ltd.

Sigma Aldrich - 76044

Other Notes
综述1,2
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Sigma Aldrich - 205869

Application
芳基溴与醇的发生分子内偶联反应生成 1,3-氧氮杂卓的催化剂。1通过钯催化分子内环化反应制备环脲。2
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
包装
1, 2, 10, 25 g in glass bottle

Sigma Aldrich - 685593

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
ChemDose: Convenient Dosing of Catalysts and Reagents
法律信息
ChemDose 商标 Reaxa Ltd.