bis((1s,4s)-bicyclo[2.2.1]hepta-2,5-diene); bis(chlororhodium)

• ChemBase编号: 139982
• 分子式: C14H16Cl2Rh2
• 平均质量: 460.99384
• 单一同位素质量: 459.87391387
• SMILES: C1[C@H]2C=C[C@@H]1C=C2.C1[C@H]2C=C[C@@H]1C=C2.Cl[Rh].Cl[Rh]
• Canonical SMILES: C1=C[C@@H]2C[C@H]1C=C2.C1=C[C@@H]2C[C@H]1C=C2.[Rh]Cl.[Rh]Cl
• InChI: InChI=1S/2C7H8.2ClH.2Rh/c2*1-2-7-4-3-6(1)5-7;;;;/h2*1-4,6-7H,5H2;2*1H;;/q;;;;2*+1/p-2/t2*6-,7+
• InChIKey: RXDWVIOULPVOEO-SEGRDSFWSA-L

名称和登记号

名称

• IUPAC标准名: bis((1s,4s)-bicyclo[2.2.1]hepta-2,5-diene); bis(chlororhodium)
• IUPAC传统名: bis((1s,4s)-bicyclo[2.2.1]hepta-2,5-diene); bis(chlororhodium)
• 别名: 二氯化二铑(双降冰片二烯); 氯化降冰片二烯铑二聚物; 降冰片二烯氯化铑二聚体; 氯降冰片二烯铑二聚体; 二氯化二铑(双降冰片二烯) 铑 44% 最低; [Rh(nbd)Cl]2; dichlorobis(norbornadiene)dirhodium; 2,5-Norbornadiene-rhodium(I) chloride dimer; Chloro(2,5-norbornadiene)rhodium(I) dimer; Rhodium(I) chloride 2,5-Norbornadiene complex dimer; Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer; Chloro(norbornadiene)rhodium(I) dimer; Di-mu-chlorobis(norbornadiene)dirhodium(I)

登记号

• CAS号: 12257-42-0
• EC号: 235-510-4
• MDL号: MFCD00198060
• PubChem SID: 24855024

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 1.6093123
• LogD (pH = 7.4): 1.6093123
• Log P: 1.6093123
• 摩尔折射率: 32.5332 cm^3
• 极化性: 11.724419 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 外观: Powder

安全信息

• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 德国WGK号: 3
• 危险公开号: 36/37/38
• 安全公开号: 26-37
• TSCA收录: 否
• GHS危险品标识: GHS07
• GHS危险声明: H315-H319-H335
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 个人保护装置: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

产品相关信息

• 纯度: 96%; Rh 44% min
• Empirical Formula (Hill Notation): C14H16Cl2Rh2

详细说明

Sigma Aldrich - 249939

包装
500 mg in glass bottle
Application
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisHydrosilylation Catalysts

Sigma Aldrich - 683167

Application
Catalyst for valence isomerization and N-heterocyclization; incombination with phosphorus ligands are catalysts for hydrogenationof many functional groups and hydroformylation; withchiral ligands are catalysts for asymmetric hydrogenation
Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisHydrosilylation Catalysts
包装
2 g in glass bottle
500 mg in glass bottle
Legal Information
Umicore 产品。