alumane nickel

• ChemBase编号: 138573
• 分子式: AlNi
• 平均质量: 85.674938
• 单一同位素质量: 84.91688153
• SMILES: [AlH3].[Ni]
• Canonical SMILES: [AlH3].[Ni]
• InChI: InChI=1S/Al.Ni
• InChIKey: NPXOKRUENSOPAO-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: alumane nickel
• IUPAC传统名: alumane nickel
• 别名: 海绵镍; Raney®-镍; 铝镍合金催化剂; 镍铝; Raney® 镍合金; 镍铝合金; 铝镍合金; Raney Ni; Nickel sponge; Raney®-Nickel; Aluminum-nickel catalyst; Nickel aluminum; Nickel-aluminum alloy; Raney®-Nickel alloy; Aluminum-nickel alloy; Aluminum Nickel

登记号

• CAS号: 7440-02-0; 12635-27-7; 12003-78-0
• EC号: 234-439-6
• MDL号: MFCD00167392
• PubChem SID: 24873470; 24886372; 24853255; 24873472; 24873469; 162232826; 24853256
• PubChem CID: 6336846

理论计算性质

• 质子受体: 0
• 质子供体: 0
• Log P: 0.472
• 摩尔折射率: 2.4 cm^3
• 极化性: 3.2326243 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true
• LogD (pH = 5.5): 0.472
• LogD (pH = 7.4): 0.472

分子性质

理化性质

• 外观: -100+325 Mesh Powder, Intermetallic; Powder; slurry
• 密度: 3.46 g/mL at 25 °C(lit.)
• pH值: 8.5-12.0

安全信息

• 欧盟危险性物质标志: 易燃性(Flammable) (F); 有毒(Toxic) (T); X; 有害性(Harmful) (Xn)
• 联合国危险货物编号: 1378; 3089; UN3089
• 德国WGK号: 2; 3
• 联合国危险货物等级: 4.1; 4.2
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 11-40-43; 15-40-43; 17-40-43-48/23; 40-42/43
• 安全公开号: 15-26-28-36/37/39; 23-36/37; 36/37; 36/37-43; 36/37-60
• TSCA收录: 是
• GHS危险品标识: GHS02; GHS07; GHS08
• GHS警示词: Danger
• GHS危险声明: H228-H317-H351; H228-H351-H317; H250-H317-H351-H372; H250-H317-H351-H372-H412; H334-H317-H351
• GHS警示性声明: P210-P241-P302+P352-P321-P405-P501A; P210-P280; P222-P231-P273-P280-P314-P422; P222-P231-P280-P314-P422; P285-P261-P302+P352-P321-P405-P501A
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1378 4.2/PG 2; UN 3089 4.1/PG 2

产品相关信息

• 纯度: 50% Al basis; 50% Ni basis; 99.0% min (metals basis)
• 浓度: in H2O
• 级别: purum
• 主要成分: Al-Ni, 50:50 wt. %; Ni, ≥89%
• 杂质: 6-9% Al
• 线性分子式: AlNi
• Empirical Formula (Hill Notation): AlNi

详细说明

Sigma Aldrich - 221651

Application
Raney 型合金，用于制备 Raney® 镍催化剂。
Catalyst for:
• Reduction reactions1
• Reductive dehalogenation and ring saturation reactions2Used for:
• Preparation of aluminum oxy-hydrate supported NiAl skeleton catalyst for hydrogenation reactions3
包装
100 g in glass bottle
法律信息
Raney 注册商标 W.R. Grace & Co.-Conn.

Sigma Aldrich - 221678

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
适于用作芳基、烯基、氰基和硝基还原的加氢催化剂。
包装
100, 500 g in poly bottle
法律信息
Raney 注册商标 W.R. Grace & Co.-Conn.

Sigma Aldrich - 510068

Application
Useful as a selective reducing agent for hydrogenation of organic compounds
包装
100, 500 g in poly bottle
法律信息
Raney 注册商标 W.R. Grace & Co.-Conn.

Sigma Aldrich - 510033

Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
包装
100, 500 g in poly bottle
法律信息
Raney 注册商标 W.R. Grace & Co.-Conn.

Sigma Aldrich - 510041

Application
Used as reducing agent for hydrogenation of organic compounds, e.g. hydrogenation of nitriles to amines, reduction of aromatic groups to the corresponding saturated compounds, hydrogenation reaction of β-keto esters, rreduction of amination, and also used as 3-alkylation of oxindole with alcohol, and Ullman-type cross coupling, and dehalogenation reactions.
包装
100 g in poly bottle
法律信息
Raney 注册商标 W.R. Grace & Co.-Conn.

Sigma Aldrich - 72240

法律信息
Raney 注册商标 W.R. Grace & Co.-Conn.