sodiumamine

• ChemBase编号: 137152
• 分子式: H2NNa
• 平均质量: 39.01235
• 单一同位素质量: 39.00849335
• SMILES: N[Na]
• Canonical SMILES: N[Na]
• InChI: InChI=1S/H2N.Na/h1H2;/q-1;+1
• InChIKey: ODZPKZBBUMBTMG-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: sodiumamine
• IUPAC传统名: sodiumamine
• 别名: 氨基钠; Sodium amide

登记号

• CAS号: 7782-92-5
• EC号: 231-971-0
• MDL号: MFCD00011117
• PubChem SID: 162231417; 24867092; 24857437; 24857541; 24852506
• PubChem CID: 24533

理论计算性质

• 质子受体: 1
• 质子供体: 1
• LogD (pH = 5.5): -2.078919
• LogD (pH = 7.4): -1.8428185
• Log P: -1.8388
• 摩尔折射率: 5.2841 cm^3
• 极化性: 3.904275 Å^3
• 极化表面积: 26.02 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 外观: crystalline
• 熔点: 210 °C(lit.)
• 沸点: 400 °C(lit.)
• 闪点: 29 °C; 39.2 °F; 4 °C; 84.2 °F

安全信息

• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 易燃性(Flammable) (F); 环境危害性(Nature polluting) (N)
• 联合国危险货物编号: 1390; 3129
• 德国WGK号: 2
• 联合国危险货物等级: 4.3
• 联合国危险货物包装类别(PG): 1; 2
• 危险公开号: 10-14/15-19-20/21-29-34-50; 14/15-19-29-34-50; 63-11-14/15-19-29-34-48/20-50-65-67
• 安全公开号: 26-36/37/39-43-45-61; 26-36/37/39-43-45-61-62
• GHS危险品标识: GHS02; GHS05; GHS07; GHS08; GHS09
• GHS警示词: Danger
• GHS危险声明: H225-H261-H304-H314-H336-H361d-H373-H400; H226-H261-H314-H400; H261-H314-H400
• GHS警示性声明: P210-P231 + P232-P261-P273-P280-P422; P231 + P232-P273-P280-P305 + P351 + P338-P310-P422
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1390 4.3/PG 2; UN 3129 4.3/PG 1; UN 3129 4.3/PG 2
• 欧盟补充危害声明: Contact with water liberates toxic gas., May form explosive peroxides.

产品相关信息

• 纯度: ≥95.0% (T); 95%; 98%
• 浓度: 50 wt. % suspension in toluene; 50 wt. % suspension in xylenes
• 级别: CP; hydrogen-storage grade; purum
• 线性分子式: NaNH2

详细说明

Sigma Aldrich - 208329

包装
50, 250 g in glass bottle
Application
Reagent for: Synthesis of allylic amines and amides1 Synthesis of antibacterials2 Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Sigma Aldrich - 432504

包装
25, 100 g in glass bottle
Application
Reagent for synthesis of: Allylic amines and amides1 Antibacterials2 Reagent for: Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Sigma Aldrich - 291587

包装
100, 750 g in glass bottle
Application
Reagent for: Synthesis of allylic amines and amides1 Synthesis of antibacterials2 Aggregative activation and heterocyclic chemistry3 Phenylation with diphenyliodonium chloride4

Sigma Aldrich - 686042

Analysis Note
可按要求提供氢含量、XRD 谱图和金属纯度数据。
包装
10 g in glass bottle