lithium(1+) ion tris(tert-butoxy)alumanuide

• ChemBase编号: 135473
• 分子式: C12H27AlLiO3
• 平均质量: 253.263518
• 单一同位素质量: 253.1935629
• SMILES: [Li+].CC(C)(C)O[Al-](OC(C)(C)C)OC(C)(C)C
• Canonical SMILES: CC(O[Al-](OC(C)(C)C)OC(C)(C)C)(C)C.[Li+]
• InChI: InChI=1S/3C4H9O.Al.Li/c3*1-4(2,3)5;;/h3*1-3H3;;/q3*-1;+2;+1
• InChIKey: FMSXILLOKUGXFX-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: lithium(1+) ion tris(tert-butoxy)alumanuide
• IUPAC传统名: lithium(1+) ion tris(tert-butoxy)alumanuide
• 别名: 三叔丁氧基氢化铝锂 溶液; 氢化三叔丁醇铝酸锂; 三叔丁氧基氢化铝锂; 氢化三叔丁醇铝锂, 通常1M THF溶液, 氩气下可重封的ChemSeal™瓶包装; Lithium tri-tert-butoxyaluminum hydride solution; Lithium aluminum-tri-tert-butoxyhydride; Lithium tri-tert-butoxyaluminum hydride; Lithium hydridotris(tert-butoxy)aluminate; Lithium tri-tert-butoxyaluminum hydride, nominally 1M in THF

登记号

• CAS号: 17476-04-9
• EC号: 241-490-8
• MDL号: MFCD00011532
• Beilstein号: 5796791
• PubChem SID: 24854741; 24896329; 24854332; 162229747
• PubChem CID: 16688073

理论计算性质

• 质子受体: 3
• 质子供体: 0
• LogD (pH = 5.5): 4.2005
• LogD (pH = 7.4): 4.2005
• Log P: 4.2005
• 摩尔折射率: 63.3575 cm^3
• 极化性: 27.776531 Å^3
• 极化表面积: 27.69 Å^2
• 可自由旋转的化学键: 6
• 里宾斯基五规则: true

分子性质

理化性质

• 外观: Liquid
• 熔点: 300-319 °C (dec.)(lit.)
• 闪点: 1.4 °F; -17 °C; -17°C(1°F); 35 °C; 95 °F
• 密度: 0.904; 0.904 g/mL at 25 °C; 0.942 g/mL at 25 °C

安全信息

• 保存注意事项: Moisture Sensitive
• RTECS编号: OJ5585000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 易燃性(Flammable) (F); 有毒(Toxic) (T)
• 联合国危险货物编号: 1409; 3399; UN3399
• 德国WGK号: 1
• 联合国危险货物等级: 4.3
• 联合国危险货物包装类别(PG): 1; I
• 危险公开号: 11-14/15-19-34-37; 11-14/15-34; 14/15-34; 60-61-10-14/15-19-34
• 安全公开号: 16-26-36/37/39-43-45; 16-26-36/37/39-43-45-60; 16-26-36/37/39-45; 53-26-36/37/39-43-45
• TSCA收录: 是
• GHS危险品标识: GHS02; GHS05; GHS07; GHS08
• GHS警示词: Danger
• GHS危险声明: H225-H260-H314-H335; H225-H260-H314-H351-H335; H226-H260-H314-H360FD; H260-H314
• GHS警示性声明: P201-P223-P231 + P232-P280-P370 + P378-P422; P210-P223-P231 + P232-P261-P370 + P378-P422; P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501A; P223-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1409 4.3/PG 1; UN 3399 4.3/PG 1
• 欧盟补充危害声明: May form explosive peroxides., Reacts violently with water.; Reacts violently with water.
• 保存温度: 2-8°C

产品相关信息

• 纯度: 97%
• 浓度: ~1.1 M in THF; 0.5 M in 2-methoxyethyl ether; 1.0 M in THF; nominally 1M in THF
• 级别: technical
• 包装: packaged under Argon in resealable ChemSeal? bottles
• 线性分子式: LiAlH[OC(CH3)3]3

详细说明

Sigma Aldrich - 241814

包装
100, 800 mL in Sure/Seal™
Application

• Reducing agent1

Sigma Aldrich - 245577

包装
100 mL in Sure/Seal™
Application

• Reducing agent1

Sigma Aldrich - L2904

包装
5, 25, 100 g in glass bottle
Application

• Reducing agent1

Sigma Aldrich - 62433

Caution
储存时可能变混浊
Application

• Reducing agent1