tetrakis((nitrooxy)bismuthanediol); hydroxybismuthanone

• ChemBase编号: 130872
• 分子式: Bi5H9N4O22
• 平均质量: 1461.98706
• 单一同位素质量: 1461.87283295
• SMILES: [N+](=O)([O-])O[Bi](O)O.[N+](=O)([O-])O[Bi](O)O.[N+](=O)([O-])O[Bi](O)O.[N+](=O)([O-])O[Bi](O)O.O[Bi]=O
• Canonical SMILES: O[Bi](O[N+](=O)[O-])O.O[Bi](O[N+](=O)[O-])O.O[Bi](O[N+](=O)[O-])O.O[Bi](O[N+](=O)[O-])O.O[Bi]=O
• InChI: InChI=1S/5Bi.4NO3.9H2O.O/c;;;;;4*2-1(3)4;;;;;;;;;;/h;;;;;;;;;9*1H2;/q+1;4*+3;4*-1;;;;;;;;;;/p-9
• InChIKey: OAVDTZZNYFIIGB-UHFFFAOYSA-E

名称和登记号

名称

• IUPAC标准名: tetrakis((nitrooxy)bismuthanediol); hydroxybismuthanone
• IUPAC传统名: tetrakis((nitrooxy)bismuthanediol); hydroxybismuthanone
• 别名: 碱性硝酸铋,Bi2O3; 次硝酸铋(III); 次硝酸铋(III); 硝酸氧化铋; 硝酸氧铋(III); 碱式硝酸铋(III); 次硝酸铋; 次硝苍; 硝酸氧铋; 碱性硝酸铋; Bismuth subnitrate; Bismuth hydroxide nitrate oxide, Bi2O3; Bismuth oxynitrate; Bismuth(III) nitrate basic; Bismuthyl nitrate; Bismuth(III) oxynitrate; Bismuth(III) subnitrate; Bismuth subnitrate; Bismuth nitrate oxide

登记号

• CAS号: 10361-46-3; 1304-85-4
• EC号: 233-792-3; 215-136-8
• MDL号: MFCD00064844
• 默克索引号: 141284
• PubChem SID: 162225150; 24858808; 24846607; 24891519; 24890148
• PubChem CID: 16717608

理论计算性质

• Acid pKa: 17.20861
• 质子受体: 5
• 质子供体: 2
• LogD (pH = 5.5): -0.25320002
• LogD (pH = 7.4): -0.2532
• Log P: -0.2532
• 摩尔折射率: 13.3836 cm^3
• 极化性: 13.855407 Å^3
• 极化表面积: 92.83 Å^2
• 可自由旋转的化学键: 8
• 里宾斯基五规则: false

分子性质

理化性质

• 溶解度: Practically insoluble in water and alcohol. Soluble in dilute HNO3 and HCl
• 外观: Powder
• 熔点: 260°C dec.
• 密度: 6.04

安全信息

• 保存注意事项: Hygroscopic
• RTECS编号: EB2977000
• 欧盟危险性物质标志: 氧化性(Oxidising) (O); 刺激性(Irritant) (Xi)
• 联合国危险货物编号: 1477; UN1477
• 德国WGK号: 3
• 联合国危险货物等级: 5.1
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 8-36/37/38
• 安全公开号: 17-26-36; 17-26-36/37/39; 17-26-37
• TSCA收录: 是
• GHS危险品标识: GHS03; GHS07
• GHS警示词: Danger
• GHS危险声明: H272-H315-H319-H335
• GHS警示性声明: P220-P261-P305 + P351 + P338; P221-P210-P305+P351+P338-P302+P352-P405-P501A
• 个人保护装置: dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1477 5.1/PG 2

产品相关信息

• 纯度: 71-74% Bi basis (calc. on dried substance); 71-74% Bi basis (KT); 79% min; 98%
• 级别: puriss.
• 适用性: meets USP testing specifications
• 杂质: ≤0.01% ammonium (NH4); ≤0.5% sub.not precip.b.NH4OH(SO4); residual solvents, complies
• 痕量阳离子: Ag: ≤0.0025%; As: ≤2 mg/kg; Ca: ≤50 mg/kg; Cd: ≤50 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe: ≤50 mg/kg; K: ≤100 mg/kg; Na: ≤2000 mg/kg; Ni: ≤50 mg/kg; Pb: ≤20 mg/kg; Pb: ≤50 mg/kg; Zn: ≤50 mg/kg
• 痕量阴离子: chloride (Cl-): ≤100 mg/kg; chloride (Cl-): ≤200 mg/kg; sulfate (SO42-): ≤200 mg/kg; sulfate (SO42-): ≤300 mg/kg
• 干燥失重: ≤3% loss on drying, 105 °C
• 品质说明: for spectrophotometric det., Bi; meets analytical specification of DAB, USP
• 线性分子式: Bi(O)NO3; Bi5O(OH)9(NO3)4

详细说明

Sigma Aldrich - 310646

包装
5, 100, 500 g in glass bottle

Sigma Aldrich - B0426

包装
100, 500 g in glass bottle