trichlorotitanium

• ChemBase编号: 129931
• 分子式: Cl3Ti
• 平均质量: 154.226
• 单一同位素质量: 152.85450434
• SMILES: Cl[Ti](Cl)Cl
• Canonical SMILES: Cl[Ti](Cl)Cl
• InChI: InChI=1S/3ClH.Ti/h3*1H;/q;;;+3/p-3
• InChIKey: YONPGGFAJWQGJC-UHFFFAOYSA-K

名称和登记号

名称

• IUPAC标准名: trichlorotitanium
• IUPAC传统名: titanium(III) chloride
• 别名: 三氯化钛; 氯化钛(III); 氯化钛(III) 溶液; Titanium(III) chloride; Titanium(III) chloride solution; titanium trichloride; titanous chloride; Titanium(III) chloride

登记号

• CAS号: 7705-07-9
• EC号: 231-728-9
• MDL号: MFCD00011266
• PubChem SID: 24873756; 24848453; 24883265; 24853202; 162224217; 24855027
• PubChem CID: 62646
• Chemspider ID: 56398
• 维基百科标题: Titanium(III)_chloride

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 1.9035
• LogD (pH = 7.4): 1.9035
• Log P: 1.9035
• 摩尔折射率: 18.4089 cm^3
• 极化性: 9.8386755 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: soluble in acetone, acetonitrile, certain amines; ; insoluble in ether and hydrocarbons; very soluble in water
• 外观: crystalline; powder; red-violet crystals ; hygroscopic; solution
• 熔点: 425 °C (decomposes); 440 °C (dec.)(lit.)
• 沸点: 960 °C
• 密度: 1.192 g/mL at 25 °C; 2.64 g/cm^3
• 折射率: 1.4856

安全信息

• RTECS编号: XR1924000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 易燃性(Flammable) (F)
• 联合国危险货物编号: 2441; 3264
• 德国WGK号: 3
• 联合国危险货物等级: 4.2; 8
• 联合国危险货物包装类别(PG): 1; 2
• 危险公开号: 14-17-34; 14-17-34-37; 34-37
• 安全公开号: 26-36/37/39-45; 6-26-30-36/37/39-43-45
• 欧盟危险品索引: Not listed
• GHS危险品标识: GHS02; GHS05; GHS07
• GHS警示词: Danger
• 主要危害: Corrosive
• GHS危险声明: H250-H314; H250-H314-H335; H314-H335
• GHS警示性声明: P222-P231-P261-P280-P305 + P351 + P338-P422; P222-P231-P280-P305 + P351 + P338-P310-P422; P261-P280-P305 + P351 + P338-P310; P261-P280-P305 + P351 + P338-P422
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2441 4.2/PG 1; UN 3264 8/PG 2
• 欧盟补充危害声明: Reacts violently with water.

产品相关信息

• 纯度: ≥12% TiCl3 basis; ≥99.99%; ≥99.995% trace metals basis
• 浓度: ~10 wt. % in 20-30 wt. % hydrochloric acid; ≥20.0%; 12% in hydrochloric acid
• 级别: hydrogen-storage grade; JIS special grade; ReagentPlus®
• 杂质: 5-10% free acid (as HCl)
• 线性分子式: TiCl3

详细说明

Sigma Aldrich - 249998

Other Notes
精确浓度见标签
包装
25, 500 mL in glass bottle
Application
Catalyst for: Hydrogen desorption properties1 Nitrogen-nitrogen reductive bond cleavage2Reagent for: Photocatalyst synthesis3 Preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeleton4

Sigma Aldrich - 220973

Application
Used with tert-butylhydroperoxide in an alcoholic solvent to promote the reductive coupling of aryl aldehydes to 1,2-diols.Catalyst for: hydrogen desorption properties Nitrogen-nitrogen reductive bond cleavageReagent for photocatalyst synthesisPrecursor for the preparation of nanostructures titania/cetyltrimethyammonium bromide nanoskeletons
用于气相形成具有超细粒度的金属间化合物。1
包装
5, 25 g in glass bottle
法律信息
ReagentPlus 注册商标 Sigma-Aldrich Co. LLC

Sigma Aldrich - 686085

Analysis Note
可索取 X 射线衍射图和金属纯度数据。
Application
用于气相形成具有超细粒度的金属间化合物。1
包装
1 g in glass bottle

Sigma Aldrich - 643394

Application
用于 CDC 认证方法。
Other Notes
精确浓度见标签

Sigma Aldrich - 514381

Application
用于气相形成具有超细粒度的金属间化合物。1
包装
1, 5 g in glass bottle

Sigma Aldrich - 14010

Application
Catalyst for hydrogen desorption1 and nitrogen-nitrogen bond cleavage2Reagent for photocatalyst synthesis3Precursor for preparation of nanostructures for nanoskeletons4