iodochlorane

• ChemBase编号: 127833
• 分子式: ClI
• 平均质量: 162.35747
• 单一同位素质量: 161.87332568
• SMILES: ClI
• Canonical SMILES: ClI
• InChI: InChI=1S/ClI/c1-2
• InChIKey: QZRGKCOWNLSUDK-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: iodochlorane
• IUPAC系统名: Chloroiodane
• IUPAC传统名: iodine monochloride
• 别名: 单氯化碘; 单氯化碘, ACS; 一氯化碘 溶液; 根据 Wijs 方法测定碘值的碘溶液; 氯化碘 溶液; 氯化碘; 一氯化碘; 单氯化碘溶液; 氯化碘 溶液; 一氯化碘 溶液; 单氯化碘溶液; Iodine monochloride, ACS; Iodine according to Wijs for the iodine value determination; Iodine monochloride solution; Wijs solution; Chloroiodide; Iodine monochloride; Chloroiodide solution; Wijs solution; Iodine monochloride solution; Iodine chloride; Iodine monochloride; Wijs' chloride; Iodine monochloride, approx. 0.22N soln. in glacial acetic acid

登记号

• CAS号: 7790-99-0
• EC号: 232-236-7
• MDL号: MFCD00011354
• Beilstein号: 3902972; 3587194
• 默克索引号: 145017
• PubChem SID: 24865151; 24852499; 24857507; 162222151; 24871766; 24861740
• PubChem CID: 24640
• Chemspider ID: 23042
• 医学主题词(MeSH): Iodine-monochloride
• 维基百科标题: Iodine_monochloride

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 1.2209004
• LogD (pH = 7.4): 1.2209004
• Log P: 1.2209004
• 摩尔折射率: 19.4771 cm^3
• 极化性: 8.258989 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: hydrolysis in water; soluble in carbon disulfide; acetic acid; pyridine ; alcohol, ether, HCl; Soluble in water, alcohol, ether, carbon disulfide
• 外观: Crystalline/Liquid; Liquid; red to brown liquid or solid
• 熔点: 25-27°C; 27.2°C (α-form) ; 13.9 °C (β-form)
• 沸点: 96-98°C; 97.4 °C(lit.); 97.4°C (370.6 K)
• 闪点: 104 °F; 105 °F; 40 °C; 41 °C
• 密度: 1.143 g/mL at 25 °C; 1.42 g/mL at 25 °C; 3.10 g/cm^3; 3.182; 3.1822; 3.24 g/mL at 25 °C(lit.)

安全信息

• 保存注意事项: Moisture & Light Sensitive
• RTECS编号: NN1650000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); X
• 联合国危险货物编号: 1792; 2789; 2920; 3264; UN1792; UN2920
• 德国WGK号: 2; 3
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 10-35; 10-35-42; 21/22-34; 34-40-42; 34-42
• 安全公开号: 20-23-26-36/37/39-45-60; 23.2-26-36/37/39-45; 23-26-36/37/39-45; 26-36/37/39-45
• TSCA收录: 是
• GHS危险品标识: GHS02; GHS05; GHS07; GHS08
• GHS警示词: Danger
• 主要危害: corrosive
• GHS危险声明: H226-H314; H314-H226-H312-H303; H314-H318-H302-H312; H314-H334; H314-H334-H351
• GHS警示性声明: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A; P261-P280-P305 + P351 + P338-P310; P280-P303+P361+P353-P305+P351+P338-P310; P280-P305 + P351 + P338-P310
• 个人保护装置: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1792 8/PG 2; UN 2789 8/PG 2; UN 2920 8/PG 2; UN 3264 8/PG 2
• 保存温度: 2-8°C

产品相关信息

• 纯度: ≥95%; ≥98% (iodometric); 1.10±0.1 I/Cl ratio basis; 99.998% trace metals basis
• 浓度: 0.1 M ICl; 1 M in acetic acid; 1.0 M in methylene chloride
• 级别: ACS reagent; reagent grade
• 杂质: <20 ppm total metallic impurities; ≤0.005% insolubles; acetic acid
• 品质说明: volumetric
• 线性分子式: ICl

详细说明

Sigma Aldrich - 714836

包装
100 mL in Sure/Seal™

Sigma Aldrich - 481556

Features and Benefits
符合 A.C.S. 试剂规范。
包装
5, 25 g in glass bottle

Sigma Aldrich - 35071

Caution
储存条件有限
General description
请访问我们的 滴定中心 了解更多信息。

Sigma Aldrich - 208221

包装
5, 100, 250 g in glass bottle

Sigma Aldrich - 34-0015

Suitability
for the iodine value determination

Sigma Aldrich - 402990

包装
25, 100 g in glass bottle

Sigma Aldrich - 291048

包装
100, 800 mL in Sure/Seal™

参考文献

• More powerful electrophilic iodinating agent than iodine e.g. for aromatic substitution. For examples of its use in AcOH for aromatic iodination, see: Org. Synth. Coll., 2, 196, 343 (1943).
• The 1:1 complex with pyridine has been recommended as a mild and efficient iodinating agent for a wide range aromatic compounds: J. Chem. Res., 405 (1994). Condensed polycyclic iodides which cannot readily be prepared by direct iodination methods are formed by reaction of the same complex with the organomercurials: J. Chem. Res. (Synop.), 405 (1995).
• For use in combination with NaN₃ for the iodoazidation of an olefin, see: Org. Synth. Coll., 6, 893 (1988).
• Reacts with Benzyltrimethylammonium chloride, A16759 to form benzyltrimethylammonium dichloroiodide, a useful reagent for the iodination of phenols: Chem. Lett., 2109 (1987).