ethyldiphenylphosphane

• ChemBase编号: 112257
• 分子式: C14H15P
• 平均质量: 214.242661
• 单一同位素质量: 214.09113711
• SMILES: CCP(c1ccccc1)c1ccccc1
• Canonical SMILES: CCP(c1ccccc1)c1ccccc1
• InChI: InChI=1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
• InChIKey: WUOIAOOSKMHJOV-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: ethyldiphenylphosphane
• IUPAC传统名: phosphine, ethyldiphenyl-
• 别名: 乙二苯膦; 乙基二苯基膦; DIPHENYL ETHYL PHOSPHINE; NSC 151254; Diphenylethylphosphine; Ethyldiphenylphosphine

登记号

• CAS号: 607-01-2
• MDL号: MFCD00015170
• Beilstein号: 744253
• PubChem SID: 24860439; 162097391; 24845482
• PubChem CID: 69082

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 3.9824
• LogD (pH = 7.4): 3.9824
• Log P: 3.9824
• 摩尔折射率: 66.4955 cm^3
• 极化性: 26.402058 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 3
• 里宾斯基五规则: true

分子性质

理化性质

• 沸点: 130°C; 130-132°C/1mm; 293 °C(lit.)
• 闪点: 110 °C; 230 °F
• 密度: 1.048; 1.048 g/mL at 25 °C(lit.)
• 折射率: n20/D 1.614(lit.)

安全信息

• 保存注意事项: Air Sensitive
• RTECS编号: SY9242500
• 欧盟危险性物质标志: X; 有害性(Harmful) (Xn)
• 联合国危险货物编号: UN3278
• 德国WGK号: 3
• 联合国危险货物等级: 6.1
• 联合国危险货物包装类别(PG): III
• 危险公开号: 22-36/37/38
• 安全公开号: 26-36; 26-36/37
• TSCA收录: 否
• GHS危险品标识: GHS07
• GHS警示词: Warning
• GHS危险声明: H302-H315-H319-H335
• GHS警示性声明: P261-P305 + P351 + P338; P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 个人保护装置: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

产品相关信息

• 纯度: ≥97.0% (GC); 98%
• 级别: purum
• 线性分子式: (C6H5)2PCH2CH3

详细说明

MP Biomedicals - 05223180

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 336904

包装
2 g in glass bottle
Application
Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide1
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes2
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles3
• Dimer to monomer conversion4
• Tandem Morita-Baylis-Hillman/Michael addition reactions5
• Platinum-catalyzed cyclization6
• Regioselective and stereoselective [3+2] cycloaddition7
• Platinum-catalyzed intermolecular hydroamination8
• Hydroformylation reactions9

Sigma Aldrich - 03460

Other Notes
用于有机金属化学的配体10,11,12,13
Application
Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide1
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes2
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles3
• Dimer to monomer conversion4
• Tandem Morita-Baylis-Hillman/Michael addition reactions5
• Platinum-catalyzed cyclization6
• Regioselective and stereoselective [3+2] cycloaddition7
• Platinum-catalyzed intermolecular hydroamination8
• Hydroformylation reactions9