triphenylsilane

• ChemBase编号: 111500
• 分子式: C18H16Si
• 平均质量: 260.40514
• 单一同位素质量: 260.10212704
• SMILES: c1ccc(cc1)[SiH](c1ccccc1)c1ccccc1
• Canonical SMILES: c1ccc(cc1)[SiH](c1ccccc1)c1ccccc1
• InChI: InChI=1S/C18H16Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
• InChIKey: AKQNYQDSIDKVJZ-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: triphenylsilane
• IUPAC传统名: triphenylsilane
• 别名: 三苯基硅烷; TRIPHENYLSILANE; 1,1′,1′′-Silylidynetrisbenzene; NSC 12565; Triphenylhydrosilane; Triphenylsilane

登记号

• CAS号: 789-25-3
• EC号: 212-333-0
• MDL号: MFCD00003003
• Beilstein号: 978182
• PubChem SID: 162096837; 24889803; 24848907
• PubChem CID: 6327682

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 4.5256
• LogD (pH = 7.4): 4.5256
• Log P: 4.5256
• 摩尔折射率: 77.2229 cm^3
• 极化性: 32.587017 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 3
• 里宾斯基五规则: true

分子性质

理化性质

• 熔点: 42-44°C; 43-45 °C; 43-45 °C(lit.)
• 沸点: 152 °C/2 mmHg(lit.); 159-163°C/3mm
• 闪点: 168.8 °F; 76 °C; 76°C(169°F)

安全信息

• 保存注意事项: Air Sensitive
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi)
• 德国WGK号: 3
• 危险公开号: 36/37/38
• 安全公开号: 26; 26-37
• TSCA收录: 是
• GHS危险品标识: GHS07
• GHS警示词: Warning
• GHS危险声明: H315-H319-H335
• GHS警示性声明: P261-P305 + P351 + P338; P261-P305+P351+P338-P302+P352-P321-P405-P501A
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves

产品相关信息

• 纯度: ≥97.0% (GC); 97%; 99%
• 级别: purum
• 线性分子式: (C6H5)3SiH

详细说明

MP Biomedicals - 05219532

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 148504

包装
5, 25 g in glass bottle
Application
Reactant or reagent:
• For catalytic hydrogen deuterium exchange reactions of silanes1
• To be oxidized by carbon nanotube-gold nanohybrids2
• For hydrolysis by ruthenium complexes3
• For hydrosilylation to produce enolsilanes4
• For synthesis of bromosilanes5
• For ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives6
• Used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes7

Sigma Aldrich - 93130

Other Notes
硅烷化试剂8
Application
Reactant or reagent:
• For catalytic hydrogen deuterium exchange reactions of silanes1
• To be oxidized by carbon nanotube-gold nanohybrids2
• For hydrolysis by ruthenium complexes3
• For hydrosilylation to produce enolsilanes4
• For synthesis of bromosilanes5
• For ozone oxidation of silyl-alkenes for synthesis of α-O-silylated acyloin derivatives6
• Used to synthesize hydrido silyl and bis(silyl) bis(imidazolinylidene) nickel complexes7