dichlororuthenium; tetrakis(triphenylphosphane)

• ChemBase编号: 111461
• 分子式: C72H60Cl2P4Ru
• 平均质量: 1221.117844
• 单一同位素质量: 1220.2066028
• SMILES: Cl[Ru]Cl.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1
• Canonical SMILES: c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.c1ccc(cc1)P(c1ccccc1)c1ccccc1.Cl[Ru]Cl
• InChI: InChI=1S/4C18H15P.2ClH.Ru/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h4*1-15H;2*1H;/q;;;;;;+2/p-2
• InChIKey: OIWNHEPSSHYXTG-UHFFFAOYSA-L

名称和登记号

名称

• IUPAC标准名: dichlororuthenium; tetrakis(triphenylphosphane)
• IUPAC传统名: dichlororuthenium; tetrakis(triphenylphosphine)
• 别名: 三苯基膦氯化钌; RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE); Dichlorotetrakis(triphenylphosphine)ruthenium(II)

登记号

• CAS号: 15555-77-8
• MDL号: MFCD09039275
• PubChem SID: 24867082; 162096856
• PubChem CID: 11982093

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 5.1066
• LogD (pH = 7.4): 5.1066
• Log P: 5.1066
• 摩尔折射率: 81.6229 cm^3
• 极化性: 32.34495 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 12
• 里宾斯基五规则: false

分子性质

安全信息

• 欧盟危险性物质标志: 有害性(Harmful) (Xn)
• 德国WGK号: 3
• 危险公开号: 20/21/22
• 安全公开号: 36
• GHS危险品标识: GHS07
• GHS警示词: Warning
• GHS危险声明: H302-H312-H332
• GHS警示性声明: P280
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves

产品相关信息

• 线性分子式: [(C6H5)3P]4RuCl2

详细说明

MP Biomedicals - 05219294

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 432245

包装
1 g in glass bottle
Application
Catalyst for:
• Selective hydrogenation of maleic anhydride or succinic anhydride1
• Sythesis of portions of the natural antibiotic tetrodecamycin2
• Oxidation of hydroxamic acid3
• Hydroesterification reactions4
• Hydroboration of alkenes5
• Oxidation of sulfide6