dichloropalladium

• ChemBase编号: 111297
• 分子式: Cl2Pd
• 平均质量: 177.326
• 单一同位素质量: 175.84119136
• SMILES: Cl[Pd]Cl
• Canonical SMILES: Cl[Pd]Cl
• InChI: InChI=1S/2ClH.Pd/h2*1H;/q;;+2/p-2
• InChIKey: PIBWKRNGBLPSSY-UHFFFAOYSA-L

名称和登记号

名称

• IUPAC标准名: dichloropalladium
• IUPAC传统名: palladium chloride
• 别名: 氯化钯(II) 溶液; 氯化钯(II); Palladium(II) chloride solution; Palladium II Chloride; Palladous Chloride; NCI-C60184; PALLADIUM CHLORIDE; Palladium(II) chloride

登记号

• CAS号: 7647-10-1
• EC号: 231-596-2; 231-115-6
• MDL号: MFCD00003558
• PubChem SID: 24886928; 24852359; 24857119; 24874155; 162097070; 24848884; 24859361
• PubChem CID: 24290

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 1.269
• LogD (pH = 7.4): 1.269
• Log P: 1.269
• 摩尔折射率: 12.2726 cm^3
• 极化性: 9.574385 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 外观: powder
• 熔点: 678-680 °C(lit.)
• 密度: 1.06 g/mL at 25 °C; 4 g/mL at 25 °C(lit.)

安全信息

• RTECS编号: RT3500000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 有毒(Toxic) (T); 有害性(Harmful) (Xn)
• 联合国危险货物编号: 1789
• 德国WGK号: 3
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): 3
• 危险公开号: 22-34-43; 25-43
• 安全公开号: 26-27/28-36/37-36/37/39-45; 36/37-45
• GHS危险品标识: GHS05; GHS06; GHS07
• GHS警示词: Danger
• GHS危险声明: H301-H317; H314-H317
• GHS警示性声明: P280-P301 + P310; P280-P305 + P351 + P338-P310
• 个人保护装置: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• RID/ADR: UN 1789 8/PG 3

产品相关信息

• 纯度: ≥99.0%; ≥99.9%; 59.0% Pd basis; 59-60% palladium (Pd) basis; 59-60% Pd basis; 60% Pd basis; 99%; 99.999%
• 浓度: 5 wt. % in 10 wt. % HCl
• 级别: JIS special grade; ReagentPlus®
• 主要成分: Pd, 59-60%
• 线性分子式: PdCl2
• Empirical Formula (Hill Notation): Cl2Pd

详细说明

MP Biomedicals - 05218554

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 323373

包装
1, 5 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
用于合成半导电的含金属聚合物，在聚合物中聚吡咯主链具有最低的构象能，并且几乎成平面。1

Sigma Aldrich - 283606

包装
50 mL in glass bottle
Application
用于合成半导电的含金属聚合物，在聚合物中聚吡咯主链具有最低的构象能，并且几乎成平面。1

Sigma Aldrich - 520659

Application
与 Cu(II) 共同用作苯乙胺脱氨基反应生成苯基取代吡咯的催化剂。与 PEG 300 共同用于促进芳基氯与芳基硼酸的高效 Suzuki 偶联反应。
该材料是 Mizoroki-Heck 反应的高效催化剂2
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
包装
1, 5, 25 g in glass bottle

Sigma Aldrich - 76050

Other Notes
综述2,3
包装
1, 5, 25 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 14814

Application
Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes.
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 205885

Analysis Note
与 Cu(II) 共同用作苯乙胺脱氨基反应生成苯基取代吡咯的催化剂。2利用 PEG (300)-PdCl2 催化剂使芳基氯与芳基硼酸发生高效 Suzuki 偶联反应。3
包装
1, 5, 25, 100, 150 g in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1
法律信息
ReagentPlus 注册商标 Sigma-Aldrich Co. LLC

Sigma Aldrich - 24-0100

Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1

Sigma Aldrich - 14757

Application
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1