silver(1+) ion perchlorate

• ChemBase编号: 111275
• 分子式: AgClO4
• 平均质量: 207.3188
• 单一同位素质量: 205.85360816
• SMILES: [Ag+].[O-][Cl](=O)(=O)=O
• Canonical SMILES: [O-][Cl](=O)(=O)=O.[Ag+]
• InChI: InChI=1S/Ag.ClHO4/c;2-1(3,4)5/h;(H,2,3,4,5)/q+1;/p-1
• InChIKey: YDHABVNRCBNRNZ-UHFFFAOYSA-M

名称和登记号

名称

• IUPAC标准名: silver(1+) ion perchlorate
• IUPAC传统名: silver(1+) ion perchlorate; silver(1+) perchlorate ion
• 别名: 高氯酸银; 高酸银水合物; 高氯酸银, 无水; Perchloric acid; silver(1+) salt; Silver perchlorate; Silver perchlorate; Silver perchlorate hydrate; SILVER PERCHLORATE, ANHYDROUS; Silver perchlorate, anhydrous

登记号

• CAS号: 331717-44-3; 7783-93-9
• EC号: 231-131-3; 232-035-4
• MDL号: MFCD00149128; MFCD00003400
• 默克索引号: 148523
• PubChem SID: 162096592; 24885223
• PubChem CID: 24562
• Chemspider ID: 22968
• 维基百科标题: Silver_perchlorate

理论计算性质

• Acid pKa: -6.8919964
• 质子受体: 4
• 质子供体: 0
• LogD (pH = 5.5): -2.4740524
• LogD (pH = 7.4): -2.4740524
• Log P: -0.097653694
• 摩尔折射率: 11.9079 cm^3
• 极化性: 5.355259 Å^3
• 极化表面积: 74.27 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: 5570 g/L in water; benzene: slightly soluble; pyridine: slightly soluble; Soluble in water and many organic solvents (benzene, toluene, pyridine)
• 外观: Colorless hygroscopic crystals; Crystalline; solid
• 熔点: 485°C dec.; 486 °C (decomp.); 486 °C(lit.)
• 密度: 2.8 g/mL at 25 °C(lit.); 2.800; 2.806; 2.806 g/cm^3

安全信息

• 保存注意事项: Light Sensitive & Hygroscopic
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 环境危害性(Nature polluting) (N); 氧化性(Oxidising) (O); 有害性(Harmful) (Xn)
• 联合国危险货物编号: 1481; UN1481
• 德国WGK号: 3
• 联合国危险货物等级: 5.1
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 8-34; 8-34-50; R:8-22; R8 R34 R50
• 安全公开号: 17-26-27-36/37/39; 17-26-36/37/39-45-61; S:17-36/37/39; S15 S17 S26 S36/37/39 S45
• TSCA收录: 是
• GHS危险品标识: GHS03; GHS05; GHS09
• GHS警示词: Danger
• NFPA704:
  

  1

  2

  2

  ox
• GHS危险声明: H272-H314; H272-H314-H318-H400
• GHS警示性声明: P220-P280-P305 + P351 + P338-P310; P221-P280-P273-P303+P361+P353-P305+P351+P338-P310
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1481 5.1/PG 2

产品相关信息

• 纯度: 97%; 98%; 99.9%
• 级别: anhydrous
• 主要成分: Ag, >50.5%
• 线性分子式: AgClO4

详细说明

Sigma Aldrich - 674583

包装
5, 25 g in poly bottle

Sigma Aldrich - 449237

包装
5 g in poly bottle
Application
用于制备 3,3′-二氰基二苯基乙炔银配位网络，以研究配体对网络结构的作用，以便研制新型材料。1

参考文献

• Silver salt soluble in water and organic solvents. Used as a mild dehydrating agent for secondary and tertiary alcohols to alkenes: Chem. Lett., 287 (1972); Synth. Commun., 8, 3 (1978). Catalyst for a variety of rearrangement processes of strained systems: Synthesis, 347 (1975); Chem. Rev., 76, 461 (1976). In the presence of various Lewis acids, can be used to promote glycosidation reactions: Angew. Chem. Int . Ed., 21, 155 (1982); Chem. Rev., 93, 1503 (1993).