ruthenium(3+) ion trichloride

• ChemBase编号: 110962
• 分子式: Cl3Ru
• 平均质量: 207.429
• 单一同位素质量: 206.81090704
• SMILES: [Cl-].[Cl-].[Cl-].[Ru+3]
• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Ru+3]
• InChI: InChI=1S/3ClH.Ru/h3*1H;/q;;;+3/p-3
• InChIKey: YBCAZPLXEGKKFM-UHFFFAOYSA-K

名称和登记号

名称

• IUPAC标准名: ruthenium(3+) ion trichloride
• IUPAC传统名: ruthenium(3+) ion trichloride; ruthenium(3+) trichloride
• 别名: 氯化钌(III)水合物, Premion®; 氯化物钌(III), 无水, Premion®; 氯化钌(III)水合物, 99.9% (PGM basis), Ru 38% 最低; Ruthenium(III) chloride hydrate, Premion®; Ruthenium(III) chloride, anhydrous, Premion®; Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min; RUBIDIUM CHLORIDE

登记号

• CAS号: 10049-08-8; 14898-67-0
• EC号: 233-167-5
• MDL号: MFCD00149844; MFCD00011208
• 默克索引号: 148302
• PubChem SID: 162096029
• PubChem CID: 82323

理论计算性质

• Acid pKa: -7.0
• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 0.8327582
• LogD (pH = 7.4): 0.8327582
• Log P: 0.6123387
• 摩尔折射率: 5.6156 cm^3
• 极化性: 2.1090326 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: Insoluble in cold water. Decomposes in hot water; Very soluble in water. Soluble in alcohol, acetone
• 外观: Crystalline; Crystalline Soluble; Powder
• 熔点: >500°C dec.; 100°Cdec
• 密度: 3.110

安全信息

• 保存注意事项: Hygroscopic
• RTECS编号: VM2650000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); X
• 联合国危险货物编号: UN3260
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): III
• 危险公开号: 22-34-53
• 安全公开号: 20-26-36/37/39-45-60-61
• TSCA收录: 是
• GHS危险品标识: GHS05; GHS07
• GHS危险声明: H314-H318-H290-H302-H412; H314-H318-H290-H302-H413
• GHS警示性声明: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A

产品相关信息

• 纯度: 99.9% (PGM basis), Ru 38% min; 99.99% (metals basis); 99.99% (metals basis), Ru 48.2% min

详细说明

MP Biomedicals - 05217212

MP Biomedicals Rare Chemical collection

参考文献

• In the presence of NaOH, is a catalyst for the high-yield rearrangement of sec-allylic alcohols to saturated ketones: J. Chem. Soc., Chem. Commun., 594 (1980). In MeOH, allyl alcohols are converted to allyl ethers. The thermodynamically more stable isomer predominates: Synth. Commun., 12, 807 (1982):
  
• In the presence of 2,2'-bipyridine, catalyzes the stereospecific epoxidation of alkenes. The configuration of the alkene is retained: Tetrahedron Lett., 25, 3187 (1984).
• For a brief survey of uses of RuC₃ in Organic synthesis, see: Synlett, 1974 (2007).
• Used catalytically, in the presence of a suitable reoxidant, such as periodate or sometimes hypochlorite, RuCl₃ is a source of the powerful oxidizing agent, ruthenium(VIII) oxide, RuO₄: J. Org. Chem., 46, 3936 (1981); J. Am. Chem. Soc., 103, 464 (1981).
• Oxidations by RuO₄ include: Alkenes to carboxylic acids: J. Am. Chem. Soc., 103, 464 (1981); Org. Synth. Coll., 8, 377 (1993). In biphasic solvent systems, the reaction can also be controlled to give good yields of syn-diols: Angew. Chem. Int. Ed., 33, 2312 (1994); Chem. Eur. J., 2, 50 (1996). For an improved protocol, employing only 0.5 mol% catalyst, see: Org. Lett., 5, 3353 (2003). For oxidation of diols to carboxylic acids: J. Org. Chem., 53, 5185 (1988). `,a-Enones to carboxylic acids: J. Org. Chem., 52, 689 (1987). Alkynes to `-diketones: Helv. Chim. Acta, 71, 237 (1988). Ethers to esters: Tetrahedron Lett., 24, 3829 (1983). Amines to amides: Chem. Pharm. Bull., 36, 3125 (1988). Methylbenzenes to benzoic acids: J. Org. Chem., 51, 2880 (1986). For the oxidation of alkenes, alcohols and aromatic rings to carboxylic acids in a biphasic system, see: J. Org. Chem., 55, 1928 (1990). For discussion of the mechanism of oxidation of hydrocarbons and ethers, see: J. Phys. Org. Chem., 9, 310 (1996). In many of these oxidations, acetonitrile has been found to be superior to other solvents due to its effective coordination to the metal. Review: J. L. Courtney in Organic Syntheses by Oxidation with Metal Complexes, W. J. Mijs et al, Eds., Plenum Press, London (1986), p 445. For a review of RuO₄-catalyzed dihydroxylation, ketohydroxylation and mono oxidation, in the synthesis of diols and `-hydroxy ketones, see: Org. Biomol. Chem., 2, 2403 (2004).