nickel(2+) ion hexahydrate dinitrate

• ChemBase编号: 110777
• 分子式: H12N2NiO12
• 平均质量: 290.79488
• 单一同位素质量: 289.97436673
• SMILES: O.O.O.O.O.O.[Ni+2].[O-][N+](=O)[O-].[O-][N+](=O)[O-]
• Canonical SMILES: [O-][N+](=O)[O-].[O-][N+](=O)[O-].O.O.O.O.O.O.[Ni+2]
• InChI: InChI=1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2
• InChIKey: AOPCKOPZYFFEDA-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: nickel(2+) ion hexahydrate dinitrate; nickel(2+) ion bis(nitrooxidane) hexahydrate
• IUPAC传统名: nickel(2+) ion hexahydrate dinitrate; nickel(2+) hexahydrate dinitronate
• 别名: 硝酸镍(II)六水合物, Puratronic®; 硝酸镍(II) 六水合物; 硝酸镍(II)六水合物, tech.; Nickel(II) nitrate hexahydrate, Puratronic®; Nickel(II) nitrate hexahydrate; NICKEL NITRATE (OUS); Nickel(II) nitrate hexahydrate, tech.

登记号

• CAS号: 13478-00-7
• EC号: 236-068-5; 231-111-4
• MDL号: MFCD00149805
• 默克索引号: 146513
• PubChem SID: 162095986; 24886376; 24852072; 24886377; 24854650
• PubChem CID: 61630

理论计算性质

• Acid pKa: -1.3999903
• 质子受体: 3
• 质子供体: 0
• LogD (pH = 5.5): 0.8368004
• LogD (pH = 7.4): 0.8368004
• Log P: 0.8368004
• 摩尔折射率: 8.3471 cm^3
• 极化性: 3.4222581 Å^3
• 极化表面积: 66.2 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: Soluble in water, alcohol
• 外观: crystalline; Crystalline Aggregates; Flake; solid
• 熔点: 56 °C(lit.); 56°C; 56.7°C
• 沸点: 137°C
• 密度: 2.05; 2.05 g/ml; 2.05 g/mL at 25 °C(lit.)

安全信息

• 保存注意事项: Hygroscopic
• RTECS编号: QR7300000
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N); 氧化性(Oxidising) (O); 有毒(Toxic) (T)
• 联合国危险货物编号: 2725; UN2725
• 德国WGK号: 3
• 联合国危险货物等级: 5.1
• 联合国危险货物包装类别(PG): 3; III
• 危险公开号: 49-61-8-20/22-38-41-42/43-48/23-50/53-68; 49-61-8-20/22-38-41-42/43-48/23-68-50/53; R:8-40-43-58
• 安全公开号: 53-45-60-61; S:14-16-22-36-61
• TSCA收录: 是
• GHS危险品标识: GHS03; GHS05; GHS07; GHS08; GHS09
• GHS警示词: Danger
• GHS危险声明: H272-H302-H315-H317-H318-H332-H334-H341-H350i-H360D-H372-H410; H272-H302-H315-H317-H318-H332-H334-H341-H350i-H360-H372-H410; H272-H334-H350-H360-H372-H317-H341-H318-H315-H400-H410-H302-H332
• GHS警示性声明: P201-P220-P261-P273-P280-P305 + P351 + P338; P221-P273-P201-P308+P313-P501A
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 2725 5.1/PG 3

产品相关信息

• 纯度: ≥96%; ≥97.0% (KT); ≥98.0%; ≥98.5% (KT); 99.9985% (metals basis); 99.999% trace metals basis; Ni 19.8% min
• 级别: puriss.; puriss. p.a.; purum p.a.; SAJ special grade
• 杂质: ≤0.3% subst. not precipitated by H2S (as SO4)
• 痕量阳离子: Ca: ≤10 mg/kg; Ca: ≤50 mg/kg; Cd: ≤10 mg/kg; Cd: ≤50 mg/kg; Co: ≤100 mg/kg; Co: ≤200 mg/kg; Co: ≤500 mg/kg; Cu: ≤10 mg/kg; Cu: ≤20 mg/kg; Cu: ≤50 mg/kg; Fe: ≤10 mg/kg; Fe: ≤50 mg/kg; K: ≤100 mg/kg; K: ≤50 mg/kg; Na: ≤100 mg/kg; Na: ≤50 mg/kg; Pb: ≤10 mg/kg; Pb: ≤50 mg/kg; Zn: ≤10 mg/kg; Zn: ≤50 mg/kg; Zn: ≤500 mg/kg
• 痕量阴离子: chloride (Cl-): ≤10 mg/kg; chloride (Cl-): ≤30 mg/kg; chloride (Cl-): ≤50 mg/kg; sulfate (SO42-): ≤100 mg/kg; sulfate (SO42-): ≤50 mg/kg
• 品质说明: crystallized
• 线性分子式: Ni(NO3)2 · 6H2O

详细说明

Sigma Aldrich - 203874

包装
20, 100, 500 g in poly bottle
Application
被用作低分子量烷烃选择性氧化催化剂的"绿粉"（钼酸镍铵）的前体。1

Sigma Aldrich - 244074

包装
100, 500 g in poly bottle