lithium(1+) ion methanolate

• ChemBase编号: 106774
• 分子式: CH3LiO
• 平均质量: 37.97492
• 单一同位素质量: 38.03439427
• SMILES: [Li+].C[O-]
• Canonical SMILES: [O-]C.[Li+]
• InChI: InChI=1S/CH3O.Li/c1-2;/h1H3;/q-1;+1
• InChIKey: JILPJDVXYVTZDQ-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: lithium(1+) ion methanolate
• IUPAC传统名: LithoTab methoxide; lithium(1+) ion methoxide
• 别名: 甲醇锂 溶液; 甲氧基锂; 甲醇锂; 甲氧基锂; LITHIUM METHOXIDE; Lithium methoxide solution; Lithium methylate; Lithium methoxide

登记号

• CAS号: 865-34-9
• EC号: 212-737-7
• MDL号: MFCD00036357
• Beilstein号: 3552389
• PubChem SID: 24865594; 24882243; 24861245; 162093464
• PubChem CID: 4177230

理论计算性质

• Acid pKa: 15.775593
• 质子受体: 1
• 质子供体: 0
• LogD (pH = 5.5): -0.51857704
• LogD (pH = 7.4): -0.5185771
• Log P: -0.51857704
• 摩尔折射率: 18.8116 cm^3
• 极化性: 2.9253356 Å^3
• 极化表面积: 23.06 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 外观: powder; Powder
• 熔点: >500°C dec.
• 沸点: 64.6 °C
• 闪点: 11 °C; 12 °C; 20 °C; 51.8 °F; 53.6 °F; 68 °F
• 密度: 0.817 g/mL at 20 °C; 0.817 g/mL at 25 °C; 0.85 g/mL at 20 °C

安全信息

• 保存注意事项: Air & Moisture Sensitive
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 易燃性(Flammable) (F); 有毒(Toxic) (T)
• 联合国危险货物编号: 3206; 3274; UN3206
• 德国WGK号: 3
• 联合国危险货物等级: 3; 4.2
• 联合国危险货物包装类别(PG): 2; II
• 危险公开号: 11-14-23/24/25-34-39/23/24/25; 11-14-23/24/25-36/38-39/23/24/25; 11-14-34; R:14/15-34
• 安全公开号: 16-26-36/37/39-45; 16-26-36/37-45; 8-16-26-43-45; S:8-45
• TSCA收录: 是
• GHS危险品标识: GHS02; GHS05; GHS06; GHS08
• GHS警示词: Danger
• GHS危险声明: H225-H251-H301-H311-H314-H331-H370; H251-H314
• GHS警示性声明: P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338; P235 + P410-P280-P305 + P351 + P338-P310; P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US); Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 3206 4.2/PG 2; UN 3274 3/PG 2
• 欧盟补充危害声明: Reacts violently with water.

产品相关信息

• 纯度: ≥90% (T); 98%; 98+%
• 浓度: ~10% in methanol (T, ~2.2 M); ~4.6% in methanol (~1 M); 1.0 M in methanol
• 级别: purum; technical
• 杂质: ~2% Li2CO3 and LiOH
• 线性分子式: CH3OLi

详细说明

MP Biomedicals - 05201382

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 408794

包装
100, 800 mL in Sure/Seal™
Application
用于溶胶-凝胶法合成硼磷酸锂。1

Sigma Aldrich - 344370

包装
25, 100 g in glass bottle
Application
用于溶胶-凝胶法合成硼磷酸锂。1

Sigma Aldrich - 62562

包装
100 mL in Sure/Seal™