iron(3+) ion tris(nitrooxidane) nonahydrate

• ChemBase编号: 105006
• 分子式: FeH18N3O18
• 平均质量: 403.99722
• 单一同位素质量: 403.99347325
• SMILES: O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-]
• Canonical SMILES: [O-][N+](=O)[O-].[O-][N+](=O)[O-].[O-][N+](=O)[O-].O.O.O.O.O.O.O.O.O.[Fe+3]
• InChI: InChI=1S/Fe.3NO3.9H2O/c;3*2-1(3)4;;;;;;;;;/h;;;;9*1H2/q+3;3*-1
• InChIKey: SZQUEWJRBJDHSM-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: iron(3+) ion tris(nitrooxidane) nonahydrate; iron(3+) ion nonahydrate trinitrate
• IUPAC传统名: ferric iron nonahydrate trinitronate; iron(3+) ion nonahydrate trinitrate; iron(3+) ion nonahydrate trinitronate
• 别名: 硝酸铁(III) 水合物, Puratronic®; 硝酸铁(III) 九水合物, ACS; 硝酸铁 九水合物; 硝酸铁(III) 九水合物; Iron(III) nitrate hydrate, Puratronic®; Iron(III) nitrate nonahydrate, ACS; Ferric nitrate nonahydrate; Iron[III] nitrate; FERRIC NITRATE NONAHYDRATE; FERRIC NITRATE NONAHYDRATE ACS REAGENT GRADE; Iron(III) nitrate nonahydrate; Ferric nitrate; Nitric acid, iron(3+) salt; Iron(III) nitrate

登记号

• CAS号: 10421-48-4; 7782-61-8
• EC号: 233-899-5; 231-096-4
• MDL号: MFCD00149708
• 默克索引号: 144027
• PubChem SID: 24877671; 24894835; 24894966; 24855367; 162093307; 24858889; 24852979
• PubChem CID: 16211566; 168014
• Chemspider ID: 10670706
• 美国药典/FDA物质标识码: N8H8402XOB
• 维基百科标题: Iron(III)_nitrate

理论计算性质

• Acid pKa: -1.3999903
• 质子受体: 3
• 质子供体: 0
• LogD (pH = 5.5): 0.8368004
• LogD (pH = 7.4): 0.8368004
• Log P: 0.8368004
• 摩尔折射率: 8.3471 cm^3
• 极化性: 3.4222581 Å^3
• 极化表面积: 66.2 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: 150 g/100 mL (hexahydrate) in water; Freely soluble in water, alcohol, acetone. Slightly soluble in cold and concentrated HNO3; soluble in alcohol, acetone
• 外观: Crystalline; Crystalline Aggregates; Crystalline, Contains excess HNO3; Pale violet crystals ; hygroscopic; solid
• 熔点: 46-48 °C; 47 °C(lit.); 47.2 °C (nonahydrate); 47°C
• 沸点: 125 °C; 125 °C (nonahydrate); 125°C dec.
• 闪点: non-flammable
• 密度: 1.68 g/cm^3 (hexahydrate) ; 1.6429 g/cm^3(nonahydrate); 1.684; 1.684 g/cm^3 at 25 °C

安全信息

• 保存条件: Room Temperature (15-30°C); Room Temperature (15-30°C), Desiccate
• 保存注意事项: Moisture Sensitive
• RTECS编号: NO7175000
• 欧盟危险性物质标志: 氧化性(Oxidising) (O); 刺激性(Irritant) (Xi)
• 联合国危险货物编号: 1466; UN1466
• 德国WGK号: 1; 3
• 联合国危险货物等级: 5.1
• 联合国危险货物包装类别(PG): 3; III
• 澳大利亚Hazchem: 1Z
• 危险公开号: 8-36/37/38; 8-36/38; R:8-36/37/38
• 安全公开号: 17-26-36; 17-26-37-60; 26; S:17-20-25-26-37/39
• 欧盟危险货物分类: O2
• 欧盟危险识别号(EUHIN): 5.1B
• 美国ERG指导号: 140
• TSCA收录: 是
• 欧盟危险品索引: not listed
• GHS危险品标识: GHS03; : Ox. sol. 3; GHS07; : Acute tox. 4 (oral); Eye irrit. 1
• GHS警示词: WARNING; Warning
• NFPA704:
  

  0

  1

  0

  OX
• GHS危险声明: 272, 302, 319; H272-H315-H319; H272-H315-H319-H335
• GHS警示性声明: 210, 220, 221, 264, 270, 280, 301+312, 305+351+338, 330, 337+313, 370+378, 501; P220-P261-P305 + P351 + P338; P221-P210-P305+P351+P338-P302+P352-P321-P501A
• 个人保护装置: dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges; Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 1466 5.1/PG 3

产品相关信息

• 纯度: >98%; ≥96%; ≥97.0% (RT); ≥98%; ≥98.0%; ≥99.0%; ≥99.999% trace metals basis; 98.0-101.0%; 98.0-101.0% (ACS specification); 98+% (metals basis); 98-101% (RT); 99.99% trace metals basis; 99.999% (metals basis)
• 级别: ACS; ACS reagent; JIS special grade; puriss. p.a.; purum p.a.; REAGENT; SAJ first grade
• 适用性: suitable for cell culture
• 杂质: ≤0.005% insolubles; ≤0.1% Substances not pptd. by NH4OH (as sulfates)
• 痕量阳离子: As: ≤2 mg/kg; Ca: ≤50 mg/kg; Cd: ≤10 mg/kg; Cd: ≤50 mg/kg; Co: ≤10 mg/kg; Co: ≤50 mg/kg; Cu: ≤50 mg/kg; Fe2+: ≤20 mg/kg; K: ≤100 mg/kg; K: ≤50 mg/kg; Mg: ≤10 mg/kg; Mn: ≤200 mg/kg; Na: ≤100 mg/kg; Na: ≤50 mg/kg; Ni: ≤50 mg/kg; Pb: ≤10 mg/kg; Pb: ≤50 mg/kg; Zn: ≤10 mg/kg; Zn: ≤50 mg/kg
• 痕量阴离子: chloride (Cl-): ≤100 mg/kg; chloride (Cl-): ≤5 mg/kg; chloride (Cl-): ≤5 ppm; chloride (Cl-): ≤50 mg/kg; phosphate (PO43-): ≤50 mg/kg; sulfate (SO42-): ≤0.01%; sulfate (SO42-): ≤300 mg/kg; sulfate (SO42-): ≤50 mg/kg
• 线性分子式: Fe(NO3)3 · 9H2O

详细说明

MP Biomedicals - 02158041

Nonahydrate
Crystalline

MP Biomedicals - 02194046

Nonahydrate
ACS Reagent Grade
Purity: >98%

MP Biomedicals - 02194662

Cell Culture Reagent
Nonahydrate

Sigma Aldrich - F8508

General description
硫酸亚铁七水合物用于细胞培养，通常与转铁蛋白、柠檬酸盐或其他铁转运分子结合。
包装
100 g in poly bottle

Sigma Aldrich - 529303

包装
25 g in glass bottle
Application
这种化合物可用于制备各种有机模板磷酸铁，由于有机模板磷酸铁具有多种晶体化学性质，并且其微孔能吸收大分子，因而引起了人们的极大关注。1

Sigma Aldrich - 254223

包装
10, 50, 250 g in glass bottle
Application
这种化合物可用于制备各种有机模板磷酸铁，由于有机模板磷酸铁具有多种晶体化学性质，并且其微孔能吸收大分子，因而引起了人们的极大关注。1

Sigma Aldrich - F3002

包装
1 kg in poly bottle
500 g in poly bottle

Sigma Aldrich - 216828

包装
1, 2.5 kg in poly bottle
100, 250, 500 g in poly bottle
Application
这种化合物可用于制备各种有机模板磷酸铁，由于有机模板磷酸铁具有多种晶体化学性质，并且其微孔能吸收大分子，因而引起了人们的极大关注。1

参考文献

• Catalyst for preparation of alkali metal amides from the metals in liquid ammonia (numerous Organic Syntheses references).
• On a clay support, cleaves 2,4-dinitrophenylhydrazones: Synthesis, 439 (1985).
• For use in regioselective mononitration of phenols, see: Tetrahedron, 45, 1415 (1989). The reaction can also be carried out in an ionic liquid: Synth. Commun., 33, 961 (2003).
• Details have been given for an improved method for preparation of the useful oxidizing agent potassium ferrate(VI) by oxidation with hypochlorite, and subsequent use, supported on Montmorillonite K10 clay, for the selective oxidation of benzyl alcohol or benzylamine to benzaldehyde, thiols to disulfides, aniline to azobenzene and various oximes and hydrazones to the parent ketone: J. Org. Chem., 61, 6360 (1996).