N,N-dimethyl[(dimethylcarbamothioyl)disulfanyl]carbothioamide

• ChemBase编号: 104692
• 分子式: C6H12N2S4
• 平均质量: 240.43288
• 单一同位素质量: 239.98833239
• SMILES: CN(C)C(=S)SSC(=S)N(C)C
• Canonical SMILES: CN(C(=S)SSC(=S)N(C)C)C
• InChI: InChI=1S/C6H12N2S4/c1-7(2)5(9)11-12-6(10)8(3)4/h1-4H3
• InChIKey: KUAZQDVKQLNFPE-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: N,N-dimethyl[(dimethylcarbamothioyl)disulfanyl]carbothioamide
• IUPAC传统名: tulisan
• 别名: 二硫化双(硫羰基二甲胺); 促进剂 T; 福美双; 二硫化四甲基秋兰姆; 二硫化四甲基秋兰姆; 福美双; Bis(dimethylthiocarbamoyl) disulfide; Bis(dimethylthiocarbamyl) disulfide; Tetramethylthiuram disulfide; Tetramethylthiuram disulfide; Thiram; TMTD; N,N,N',N'-Tetramethylthioperoxydicarbonic Diamide; Tetramethyl-thiuram-disulfide; bis[Dimethylthiocarbamyl] disulfide; Thiram; TETRAMETHYLTHIURAM DISULFIDE; Thiram

登记号

• CAS号: 137-26-8
• EC号: 205-286-2
• MDL号: MFCD00008325
• Beilstein号: 1725821
• 默克索引号: 149371
• PubChem SID: 24889011; 24899172; 162091931; 24869255; 24900038
• PubChem CID: 5455
• KEGG ID: D06114
• 维基百科标题: Thiram

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 2.732527
• LogD (pH = 7.4): 2.732527
• Log P: 2.732527
• 摩尔折射率: 69.2408 cm^3
• 极化性: 27.157925 Å^3
• 极化表面积: 6.48 Å^2
• 可自由旋转的化学键: 3
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: 30 mg/L in water
• 外观: White to yellow crystalline powder
• 熔点: 146 °C; 147-152 °C; 152-155°C; 155 - 156°C; 156-158 °C(lit.)
• 沸点: 129 °C at 20 mmHg; 129°C/20mm
• 闪点: 138°C (280.4°F); 150 °C; 302 °F; 89 °C (closed cup); 89°C(192°F)
• 自燃点: 316 °F; not self-flammable
• 密度: 1.29 g/cm^3 at 20 °C; 1.300
• 蒸汽压: Negligible at room temperature, <7.5 x 10-6 mm Hg at 25 °C.

安全信息

• 保存条件: Room Temperature (15-30°C)
• RTECS编号: JO1400000
• 欧盟危险性物质标志: 环境危害性(Nature polluting) (N); X; 有害性(Harmful) (Xn)
• 联合国危险货物编号: 2811; 3077; UN3077
• 德国WGK号: 3
• 联合国危险货物等级: 6.1; 9
• 联合国危险货物包装类别(PG): 3; III
• 澳大利亚Hazchem: 2X
• 危险公开号: 20/22-36/38-43-48/22-50/53; R:20/22-36/37-40-43
• 安全公开号: 26-36/37-60-61; S:36/37
• 美国ERG指导号: 154
• TSCA收录: 是
• GHS危险品标识: GHS07; GHS08; GHS09
• GHS警示词: Warning
• GHS危险声明: H302 + H332-H315-H317-H319-H373-H410; H302-H315-H317-H319-H332-H373-H410; H373-H400-H410-H302-H332-H315-H319-H317
• GHS警示性声明: P260-P261-P305+P351+P338-P302+P352-P321-P501A; P273-P280-P305 + P351 + P338-P501
• 个人保护装置: dust mask type N95 (US), Eyeshields, Faceshields, Gloves
• RID/ADR: UN 3077 9/PG 3

产品相关信息

• 纯度: ≥98.0% (N); 97%
• 级别: analytical standard; PESTANAL®, analytical standard; purum
• 包装: ampule of 1000 mg
• 线性分子式: (CH3)2NCSS2CSN(CH3)2

详细说明

MP Biomedicals - 02156829

Crystalline
Purity: 97%

Sigma Aldrich - T24201

包装
5, 100 g in glass bottle

Sigma Aldrich - 45689

法律信息
PESTANAL 注册商标 Sigma-Aldrich Laborchemikalien GmbH

Toronto Research Chemicals - T395500

Thiram is an ectoparasiticide. Thiram is used in agriculture to prevent fungal diseases in seed and crops. Thiram has other applications ranging from use as a topical bactericide to animal repellent.

参考文献

• Sahni, M.L. et al.: Ind. Phytopathol., 20, 71 (1967)
• Vir, D.: Pesticide, 11, 39 (1967)
• Welch, J.F. et al.: Plant. Dis. Rep., 35, 57 (1967)