lithium(1+) ion iodide

• ChemBase编号: 104256
• 分子式: ILi
• 平均质量: 133.84547
• 单一同位素质量: 133.92047755
• SMILES: [Li+].[I-]
• Canonical SMILES: [Li+].[I-]
• InChI: InChI=1S/HI.Li/h1H;/q;+1/p-1
• InChIKey: HSZCZNFXUDYRKD-UHFFFAOYSA-M

名称和登记号

名称

• IUPAC标准名: lithium(1+) ion iodide
• IUPAC传统名: lithium(1+) ion iodide; LithoTab iodide
• 别名: 碘化锂; 碘化锂,超干; 碘化锂, 无水; 碘化锂, 超干; 碘化锂,无水; Lithium iodide; Lithium iodide, ultra dry; LITHIUM IODIDE; Lithium iodide, anhydrous

登记号

• CAS号: 10377-51-2
• EC号: 233-822-5
• MDL号: MFCD00011092
• 默克索引号: 145535
• PubChem SID: 24873993; 24868594; 162092470; 24867537; 24853051
• PubChem CID: 66321
• Chemspider ID: 59699
• 维基百科标题: Lithium_iodide

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 0.0
• LogD (pH = 7.4): 0.0
• Log P: 0.0
• 摩尔折射率: 0.0 cm^3
• 极化性: 1.7969184 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true
• Acid pKa: 3.09

分子性质

理化性质

• 溶解度: 151 g/100 mL (25 °C) ; 433 g/100 mL (100 °C) in water; 343 g/100 mL (20 °C) in methanol; 42.6 g/100 mL (18 °C) in acetone; Soluble in water, alcohol, acetone and methanol. Very soluble in NH4OH
• 外观: -10 Mesh Beads, Ampouled under argon; beads; crystalline powder; Crystalline/Powder, Ampouled under argon; Lumps/powder, Ampouled under argon; Powder, Ampouled under argon; White crystalline solid
• 熔点: 446 °C(lit.); 449°C; 449°C; 469 °C
• 沸点: 1170°C; 1170-1190°C; 1171 °C
• 闪点: Non-flammable
• 密度: 3.49 g/mL at 25 °C(lit.); 4.076; 4.076 g/cm^3 (anhydrous) ; 3.494 g/cm^3 (trihydrate); 4.08 g/cc
• 折射率: 1.955
• 热容: 0.381 J/g K
• 标准摩尔生成焓 (ΔfH^o298): -2.02 kJ/g

安全信息

• 保存条件: Room Temperature (15-30°C), Desiccate, Protect from light
• 保存注意事项: Light Sensitive & Hygroscopic
• 欧盟危险性物质标志: 刺激性(Irritant) (Xi); 有害性(Harmful) (Xn)
• 德国WGK号: 1; 3
• 危险公开号: 36/37/38; 36/38; R:22
• 安全公开号: 26; 26-37; S:46
• TSCA收录: 是
• 欧盟危险品索引: Not listed
• GHS危险品标识: GHS07
• GHS警示词: Warning
• GHS危险声明: H315-H319; H315-H319-H335
• GHS警示性声明: P261-P305+P351+P338-P302+P352-P321-P405-P501A; P280-P305+P351+P338-P302+P352-P321-P362-P332+P313; P305 + P351 + P338
• 个人保护装置: dust mask type N95 (US), Eyeshields, Gloves

产品相关信息

• 纯度: ≥98.0% (AT); 98+%; 99%; 99% (metals basis); 99.9% trace metals basis; 99.95% (metals basis); 99.99% trace metals basis; 99.999% (metals basis); 99.999% trace metals basis
• 级别: anhydrous; purum
• 颗粒大小: -10 mesh
• 线性分子式: LiI

详细说明

MP Biomedicals - 02155259

Produces a hazy solution at 50% (w/v) in H2O.

Sigma Aldrich - 450952

Application
控制钯催化烯丙位烷化反应的区域选择性。1
包装
5, 25 g in ampule

Sigma Aldrich - 218219

Application
控制钯催化烯丙位烷化反应的区域选择性。1
包装
10, 50, 250, 6×250 g in glass bottle

Sigma Aldrich - 439746

包装
5, 25 g in ampule
Application
控制钯催化烯丙位烷化反应的区域选择性。1

Sigma Aldrich - 518018

包装
10, 50 g in glass bottle
Protocols & Applications
Complex Hydrides: A New Category of Solid-state Lithium Fast-ion Conductors

参考文献

• Can be used in refluxing pyridine or collidine for selective cleavage of methyl esters: Rocz. Chem., 30, 323 (1956); Helv. Chim. Acta, 43, 113 (1960). For review and comparison with other methods, see: Org. React., 24, 187 (1976).
• Also cleaves aralkyl ethers in collidine: Chem. Commun., 616 (1969); J. Am. Chem. Soc., 103, 4247 (1981).
• For rearrangement of oxaspiropentane to cyclobutanone with LiI, see: Org. Synth. Coll., 6, 320 (1988).