trichloroiron

• ChemBase编号: 103901
• 分子式: Cl3Fe
• 平均质量: 162.204
• 单一同位素质量: 160.84149554
• SMILES: Cl[Fe](Cl)Cl
• Canonical SMILES: Cl[Fe](Cl)Cl
• InChI: InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
• InChIKey: RBTARNINKXHZNM-UHFFFAOYSA-K

名称和登记号

名称

• IUPAC标准名: trichloroiron
• IUPAC传统名: ferric chloride
• 别名: 氯化铁 溶液; 三氯化铁 溶液; 氯化铁; 氯化铁(III); 三氯化铁; 铁标准浓缩液 10.00g Fe; 铁原子光谱分析标准浓缩液 1.00g Fe; 三氯化铁 溶液; 色氨酸脱氨酶试剂; TDA 试剂; 硅胶负载氯化铁; 硅胶负载三氯化铁; trichloroiron; Iron Chloride; FERRIC CHLORIDE, ANHYDROUS; Ferric chloride solution; Iron(III) chloride solution; Iron(III) chloride; Chlorure Perrique; Iron (III) Chloride; Iron Trichloride; Perchlorure de Fer; FERRIC CHLORIDE; Ferric chloride; Molysite; Flores martis; Iron(III) chloride; Iron atomic spectroscopy standard concentrate 10.00 g Fe; Iron atomic spectroscopy standard concentrate 1.00 g Fe; Iron(III) chloride solution; Tryptophan Deaminase Reagent; TDA Reagent; Ferric chloride on silica gel; Iron(III) chloride on silica gel

登记号

• CAS号: 7705-08-0
• EC号: 231-729-4; 231-096-4
• MDL号: MFCD00011005
• PubChem SID: 162091653; 24845467; 24845365; 24847528; 24868641; 24849697; 24862014; 24868472
• PubChem CID: 24380
• CHEBI ID: 30808
• Chemspider ID: 22792
• 维基百科标题: Iron(III)_chloride

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): 2.3035
• LogD (pH = 7.4): 2.3035
• Log P: 2.3035
• 摩尔折射率: 18.4089 cm^3
• 极化性: 10.17752 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: 63 g/100 ml (18 °C); highly soluble; 83 g/100 ml; highly soluble in acetone; Methanol; Ethanol; Diethyl ether; 74.4 g/100 mL (0 °C) ; 92 g/100 mL (hexahydrate, 20 °C) in water; H2O: soluble
• 外观: green-black by reflected light; purple-red by transmitted light; hexahydrate: yellow solid; aq. solutions: brown; powder
• 熔点: 304 °C(lit.); 306 °C; 306 °C (anhydrous) ; 37 °C (hexahydrate); 306°C
• 沸点: 315 °C; 315 °C (anhydrous, decomp) ; 280 °C (hexahydrate, decomp) (partial decomposition to FeCl₂ + Cl₂); 315°C
• 闪点: 10 °F; -12 °C; non-flammable
• 密度: 0.868 g/mL at 25 °C; 2.898 g/cm^3 (anhydrous) ; 1.82 g/cm^3 (hexahydrate); 2.898 g/cm^3 at 25 °C
• 折射率: n20/D 1.414
• 蒸汽压: 1 mmHg ( 194 °C); 1.33 hPa at 25 °C
• 蒸汽密度: 5.61 (vs air)
• 疏水性(logP): -1.316
• 粘度: 40% solution: 12 cP
• 气味: slight HCl

安全信息

• 保存条件: Room Temperature (15-30°C), Desiccate, Store Under Nitrogen
• RTECS编号: LJ9100000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 易燃性(Flammable) (F); 刺激性(Irritant) (Xi); 有害性(Harmful) (Xn)
• 联合国危险货物编号: 1773; 1773 (anhydrous); 2582 (aq. soln.); 2536; 2582
• 德国WGK号: 1; 3
• 联合国危险货物等级: 3; 8
• 联合国危险货物包装类别(PG): 2; 3; III
• 澳大利亚Hazchem: 2X
• 危险公开号: 11-19; 22-38-41; 36; 38-41; 41; R:34; R:36/37/38
• 安全公开号: 16-23; 26; 26-39; S:20-25-26-37/39; S:26-27/28-36/37/39-46-64
• 欧盟危险货物分类: C10
• 欧盟危险识别号(EUHIN): 8B
• 美国ERG指导号: 157
• 欧盟危险品索引: listed
• GHS危险品标识: GHS05; : Corr. Met. 1; Skin Corr. 1C; Eye Dam. 1; GHS07; : Acute Tox. 4 (oral); GHS09
• GHS警示词: DANGER; Danger
• NFPA704:
  

  0

  2

  0
• GHS危险声明: 290, 302, 314, 318; H290-H302-H315-H318-H411; H290-H315-H318-H411; H290-H318-H412; H315-H318; H318-H412
• GHS警示性声明: 234, 260, 264, 270, 273, 280, 301+312, 301+330+331, 303+361+353, 363, 304+340, 310, 321, 305+351+338, 390, 405, 406, 501; P273-P280-P305 + P351 + P338; P280-P305 + P351 + P338
• 个人保护装置: dust mask type N95 (US), Eyeshields, Faceshields, Gloves; Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter; Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 1773 8/PG 3; UN 2536 3/PG 2; UN 2582 8/PG 3

产品相关信息

• 纯度: ≥97.0% (RT); ≥98%; ≥99.9% trace metals basis; ≥99.99% trace metals basis; 45% FeCl3 basis; 95%; 97%
• 浓度: 0.2 M in 2-methyltetrahydrofuran; 1.00 g/L; 10.00 g/L; 38%
• 级别: anhydrous; CP; for microbiology; purum; reagent grade; sublimed grade
• 主要成分: ferric chloride, 1 g/10 mL (in distilled water)
• 适用性: in accordance for identity
• 杂质: ≤1% insoluble in water
• 痕量阳离子: As: ≤20 mg/kg; Cu: ≤1000 mg/kg; Fe2+: ≤2000 mg/kg; Mn: ≤3000 mg/kg; Ni: ≤500 mg/kg; Pb: ≤200 mg/kg; Zn: ≤1000 mg/kg
• 有效期: (limited shelf life, expiry date on the label)
• 标签扩展内容: ~0.4 mmol/g FeCl3 loading; 5 wt. % loading
• 品质说明: ampule; anhydrous
• 线性分子式: FeCl3
• Empirical Formula (Hill Notation): Cl3Fe

详细说明

MP Biomedicals - 02153499

Anhydrous

Sigma Aldrich - 710857

Application
Used as mild oxidant for phenolic coupling, dimerizing aryllithiumsand ketone enolates; also used as mild Lewis acid to catalyzes enereactions, Nazarov cyclizations, Michael additions, andacetonations
包装
50 mL in Sure/Seal™

Sigma Aldrich - 361003

包装
25 g in poly bottle

Sigma Aldrich - 451649

包装
1, 5 g in ampule
Application
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。

Sigma Aldrich - 701122

包装
1, 5, 25 g in glass bottle
Application
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。

Sigma Aldrich - 03376

Preparation Note
用 FeCl3.6H2O 和 H2O 制备
Reconstitution
稀释时，用 HCl 或 H2SO4 进行酸化。

Sigma Aldrich - 80353

Application
For identification of Proteus species by detection of tryptophan deaminase activity.

Sigma Aldrich - 44937

Other Notes
用于多种醇类脱水的负载试剂1；用于氧化偶联反应并作为 Lewis 酸使用2,3,4

Sigma Aldrich - 02679

Preparation Note
用 FeCl3.6H2O、HCl 和 H2O 制备。
Reconstitution
用水将安瓿瓶的溶液稀释至约 850mL。小心添加 100mL 浓盐酸进行酸化。加水定容。

Sigma Aldrich - 157740

包装
1 kg in poly bottle
5 g in glass bottle
100 g in poly bottle
6×1 kg in glass bottle
Application
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。

Sigma Aldrich - 15-1190

Application
在氢作用下与其他金属卤化物气相共还原生成细分的金属互化物，它们可用作具有有效的热电性、磁性和抗氧化性的结构材料或化合物。