tetramethylazanium oxidanide

• ChemBase编号: 103547
• 分子式: C4H13NO
• 平均质量: 91.15212
• 单一同位素质量: 91.09971404
• SMILES: [OH-].C[N+](C)(C)C
• Canonical SMILES: C[N+](C)(C)C.[OH-]
• InChI: InChI=1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1
• InChIKey: WGTYBPLFGIVFAS-UHFFFAOYSA-M

名称和登记号

名称

• IUPAC标准名: tetramethylazanium oxidanide; tetramethylazanium hydroxide
• IUPAC传统名: tetramethylammonium ion OH-; tetramethylammonium oxidanide; tetramethylammonium hydroxide
• 别名: 四甲基氢氧化铵; 四甲基氢氧化铵 溶液; 四甲基氢氧化铵五水合物; Tetramethylammonium hydroxide; TMAOH; TMAH; N,N,N-Trimethylmethanaminium hydroxide; Hydroxyde de tetramethylammonium; Tetrametanoamonio hydroxido; Tetramethylammoniumhydroxid; Tetrametiloamonio hydroxido; TM; TETRAMETHYLAMMONIUM HYDROXIDE; Tetramethylammonium hydroxide solution; tetramethylammonium hydroxide; N,N,N,-trimethylmethanaminium hydroxide; Tetramethylammonium hydroxide solution; Tetramethylammonium hydroxide concentrate; Tetramethylammonium hydroxide pentahydrate

登记号

• CAS号: 75-59-2; 10424-65-4
• EC号: 200-882-9
• MDL号: MFCD00008280; MFCD00149566
• Beilstein号: 3558708; 3714235
• 默克索引号: 149224
• PubChem SID: 24860267; 24865105; 24859984; 24866695; 24861825; 24888943; 24861819; 24865174; 24859725; 24863957; 162090947; 24888944
• PubChem CID: 60966
• Chemspider ID: 54928
• 维基百科标题: Tetramethylammonium_hydroxide

理论计算性质

• 质子受体: 0
• 质子供体: 0
• LogD (pH = 5.5): -3.9721673
• LogD (pH = 7.4): -3.9721673
• Log P: -3.9721673
• 摩尔折射率: 35.9017 cm^3
• 极化性: 9.572162 Å^3
• 极化表面积: 0.0 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: high in water
• 外观: APHA: ≤10; Liquid
• 熔点: 66-67°C; 67° C (pentahydrate)
• 沸点: 100 °C; ca 102°C; decomposes
• 闪点: >100 °C; >212 °F; 10 °C; 12 °C; 12°C(54°F); 27 °C; 37.2°C; 50 °F; 53.6 °F; 80.6 °F
• 密度: ~ 1.015 g/cm^3 (20-25% aqueous solution); 0.865; 0.866 g/mL at 25 °C; 1.005 g/mL at 25 °C; 1.006 g/mL at 25 °C; 1.016; 1.016 g/ml; 1.016 g/mL at 25 °C; 1.020 g/mL at 20 °C
• 折射率: 1.3840; n20/D 1.3497; n20/D 1.351; n20/D 1.3521; n20/D 1.3806; n20/D 1.382
• 蒸汽压: 17.5 mm Hg @ 20°C; 17.5 mmHg ( 20 °C)
• 紫外吸收波长: λ: 230 nm Amax: 0.10; λ: 240 nm Amax: 0.03; λ: 250 nm Amax: 0.02; λ: 500 nm Amax: 0.02

安全信息

• 保存条件: Room Temperature (15-30°C), Store Under Nitrogen
• 保存注意事项: Air Sensitive; Air Sensitive & Hygroscopic
• RTECS编号: PA0875000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 易燃性(Flammable) (F); 有毒(Toxic) (T)
• 联合国危险货物编号: 1835; 1992; 2920; 3286; UN1835; UN2924; UN3423
• 德国WGK号: 1; 3; nwg
• 联合国危险货物等级: 3; 8
• 联合国危险货物包装类别(PG): 2; 3; II
• 澳大利亚Hazchem: 2X
• 危险公开号: 10-23/24/25-34-39/23/24/25-52; 11-23/24/25-34-39/23/24/25; 11-23/24/25-36-39/23/24/25; 21/22-34; 21-25-34-52/53; 24/25-34-52; 24/25-34-52/53; 24/25-35-52; R:21-34
• 安全公开号: 16-26-36/37/39-45; 16-26-36/37-45; 20-26-27-36/37/39-45-61; 26-36/37/39-45; 26-36/37/39-45-61; 7-16-26-36/37/39-45-61; S:26-27/28-36/37/39-46-64
• 欧盟危险货物分类: C9
• 欧盟危险识别号(EUHIN): 8B
• 美国ERG指导号: 153
• TSCA收录: 是
• GHS危险品标识: GHS02; GHS05; GHS06; GHS08
• GHS警示词: Danger
• GHS危险声明: H224-H300-H310-H330-H370-H314-H318; H225-H300-H311-H314-H331-H370; H225-H301-H311-H315-H319-H332-H336-H370; H226-H300-H311-H314-H331-H370; H300 + H310-H314; H300-H310-H314-H318-H402-H412; H300-H311-H314; H300-H312-H314; H301-H314; H301-H315-H319
• GHS警示性声明: P210-P260-P264-P280-P301 + P310-P305 + P351 + P338; P210-P260-P280-P301 + P310-P305 + P351 + P338-P307 + P311; P210-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501A; P260-P264-P280-P301 + P310-P305 + P351 + P338-P310; P260-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501A; P264-P280-P301 + P310-P302 + P350-P305 + P351 + P338-P310; P264-P280-P301 + P310-P305 + P351 + P338-P310; P280-P301 + P310-P305 + P351 + P338-P310; P301 + P310-P305 + P351 + P338
• 个人保护装置: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter; Faceshields, Gloves, Goggles
• RID/ADR: UN 1835 8/PG 2; UN 1835 8/PG 3; UN 1992 3/PG 2; UN 2920 8/PG 2; UN 3286 3/PG 2
• 保存温度: 2-8°C

产品相关信息

• 纯度: 25% w/w aq. soln., Electronic Grade, 99.9999% (metals basis); 25% w/w in methanol; 98%
• 浓度: ~1 M in H2O; ~10% in H2O (~1.1 M); ~10% in methanol (T); ~25% in H2O; ~25% in H2O (~2.8 M); 0.1 M (CH3)4NOH (0.1N); 0.1 M (CH3)4NOH in isopropanol/methanol (0.1N); 0.95-1.05 M; 1.0 M±0.02 M in H2O; 10 wt. % in H2O; 25 wt. % in H2O; 25 wt. % in methanol; 25% in H2O
• 级别: ACS reagent; for ion pair chromatography; for titration in non-aqueous medium; for trace analysis; puriss. p.a.; purum; semiconductor grade PURANAL™ (Honeywell 17741); semiconductor grade ULSI PURANAL™ (Honeywell 17032); technical; TraceSELECT®; TraceSELECT® Ultra
• 包装: pkg of 0.1 mol (9.115 g C4H13NO)
• 适用性: corresponds to standard for filter test; corresponds to standard for RP gradient test
• 燃烧残渣: ≤5 ppm
• 杂质: ≤0.1% halides (as chloride); ≤0.3% halides (as chloride); ≤10 μg/kg total-iodine; ≤10% water; ≤2% chloride; ≤3% halides (as chloride); ≤5 μg/kg total iodine
• 痕量阳离子: Ag: ≤0.01 μg/kg; Ag: ≤0.5 μg/kg; Al: ≤1 μg/kg; Al: ≤5 μg/kg; As: ≤0.05 μg/kg; As: ≤0.5 μg/kg; Au: ≤0.01 μg/kg; Au: ≤1 μg/kg; Ba: ≤0.05 μg/kg; Ba: ≤0.5 μg/kg; Be: ≤0.05 μg/kg; Be: ≤0.5 μg/kg; Bi: ≤0.1 μg/kg; Bi: ≤0.5 μg/kg; Ca: ≤10 μg/kg; Ca: ≤2 μg/kg; Cd: ≤0.01 μg/kg; Cd: ≤0.5 μg/kg; Ce: ≤0.01 μg/kg; Ce: ≤0.5 μg/kg; Co: ≤0.01 μg/kg; Co: ≤0.5 μg/kg; Cr: ≤0.2 μg/kg; Cr: ≤1 μg/kg; Cs: ≤0.01 μg/kg; Cs: ≤0.5 μg/kg; Cu: ≤0.5 μg/kg; Dy: ≤0.01 μg/kg; Er: ≤0.01 μg/kg; Eu: ≤0.01 μg/kg; Fe: ≤0.5 μg/kg; Fe: ≤5 μg/kg; Ga: ≤0.01 μg/kg; Ga: ≤0.5 μg/kg; Gd: ≤0.01 μg/kg; Ge: ≤0.01 μg/kg; Ge: ≤0.5 μg/kg; Hf: ≤0.01 μg/kg; Hg: ≤0.5 μg/kg; Ho: ≤0.01 μg/kg; In: ≤0.01 μg/kg; In: ≤0.5 μg/kg; K: ≤1 μg/kg; K: ≤10 μg/kg; K: ≤2 ppm; La: ≤0.01 μg/kg; Li: ≤0.01 μg/kg; Li: ≤0.5 μg/kg; Lu: ≤0.01 μg/kg; Mg: ≤0.2 μg/kg; Mg: ≤0.5 μg/kg; Mn: ≤0.05 μg/kg; Mn: ≤0.5 μg/kg; Mo: ≤0.1 μg/kg; Mo: ≤0.5 μg/kg; Na: ≤10 μg/kg; Na: ≤2 ppm; Na: ≤2 μg/kg; Nb: ≤0.01 μg/kg; Nd: ≤0.01 μg/kg; Ni: ≤0.1 μg/kg; Ni: ≤1 μg/kg; Os: ≤0.1 μg/kg; Pb: ≤1 μg/kg; Pb: ≤5 μg/kg; Pd: ≤0.01 μg/kg; Pr: ≤0.01 μg/kg; Pt: ≤0.01 μg/kg; Pt: ≤0.5 μg/kg; Rb: ≤0.01 μg/kg; Rb: ≤0.5 μg/kg; Re: ≤0.01 μg/kg; Rh: ≤0.01 μg/kg; Ru: ≤0.01 μg/kg; Sb: ≤0.05 μg/kg; Sb: ≤0.5 μg/kg; Sc: ≤0.05 μg/kg; Se: ≤0.5 μg/kg; Se: ≤1 μg/kg; Sm: ≤0.01 μg/kg; Sn: ≤0.05 μg/kg; Sn: ≤0.5 μg/kg; Sr: ≤0.01 μg/kg; Sr: ≤0.5 μg/kg; Tb: ≤0.01 μg/kg; Te: ≤0.01 μg/kg; Th: ≤0.01 μg/kg; Ti: ≤0.5 μg/kg; Ti: ≤1 μg/kg; Tl: ≤0.01 μg/kg; Tl: ≤0.5 μg/kg; Tm: ≤0.01 μg/kg; U: ≤0.01 μg/kg; V: ≤0.01 μg/kg; V: ≤1 μg/kg; W: ≤0.1 μg/kg; Y: ≤0.01 μg/kg; Yb: ≤0.01 μg/kg; Zn: ≤0.5 μg/kg; Zn: ≤1 μg/kg; Zr: ≤0.1 μg/kg; Zr: ≤1 μg/kg
• 痕量阴离子: bromide (Br-): ≤50 μg/kg; chloride (Cl-): ≤0.03%; chloride (Cl-): ≤50 μg/kg; fluoride (F-): ≤50 μg/kg; nitrate (NO3-): ≤250 μg/kg; phosphate (PO43-): ≤50 μg/kg; sulfate (SO42-): ≤1000 mg/kg; sulfate (SO42-): ≤500 μg/kg
• 品质说明: ampule; volumetric
• λ: in concentrate
• 线性分子式: (CH3)4N(OH)

详细说明

MP Biomedicals - 02152115

10% aqueous solution

Sigma Aldrich - 40317

法律信息
PURANAL 商标 Honeywell Specialty Chemicals Seelze GmbH

Sigma Aldrich - 40265

法律信息
PURANAL 商标 Honeywell Specialty Chemicals Seelze GmbH

Sigma Aldrich - 68556

法律信息
TraceSELECT 注册商标 Sigma-Aldrich Co. LLC

Sigma Aldrich - 87728

包装
安瓿瓶装浓缩液，用于 6×1L 0.005M 即用型溶液

Sigma Aldrich - 35436

General description
请访问我们的 滴定中心 了解更多信息。

Sigma Aldrich - 14213

法律信息
TraceSELECT 注册商标 Sigma-Aldrich Co. LLC

Sigma Aldrich - 38335

General description
concentration after dilution to 1L: 0.1mol/L (0.1N); amount of substance 0.1mol (9.115 g C4H13NO)
请访问我们的 滴定中心 了解更多信息。

Sigma Aldrich - 328251

包装
1 L in glass bottle
250 mL in glass bottle

Sigma Aldrich - 334901

包装
5, 100, 500 mL in glass bottle

Sigma Aldrich - 331635

包装
1 L in glass bottle
250 mL in glass bottle

Sigma Aldrich - 426318

包装
1 L in glass bottle
250 mL in glass bottle