1,1-diphenylhydrazine hydrochloride

• ChemBase编号: 103220
• 分子式: C12H13ClN2
• 平均质量: 220.69802
• 单一同位素质量: 220.07672611
• SMILES: Cl.NN(c1ccccc1)c1ccccc1
• Canonical SMILES: NN(c1ccccc1)c1ccccc1.Cl
• InChI: InChI=1S/C12H12N2.ClH/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12;/h1-10H,13H2;1H
• InChIKey: MIVUDWFNUOXEJM-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: 1,1-diphenylhydrazine hydrochloride
• IUPAC传统名: 1,1-diphenylhydrazine hydrochloride
• 别名: N,N-二苯肼盐酸盐(不对称); N,N-二苯肼盐酸盐; 1,1-联苯基肼 盐酸盐; N,N-二苯肼（不对称） 盐酸盐; N,N-二苯基肼 盐酸盐; N,N-Diphenylhydrazine hydrochloride (asym.); N,N-Diphenylhydrazine hydrochloride; 1,1-diphenylhydrazine hydrochloride; N,N-Diphenylhydrazine hydrochloride; 1,1-DIPHENYLHYDRAZINE; N,N-Diphenylhydrazine (asym.) hydrochloride; 1,1-Diphenylhydrazine hydrochloride

登记号

• CAS号: 530-47-2
• EC号: 208-481-0
• MDL号: MFCD00012950
• Beilstein号: 3569340
• 默克索引号: 143325
• PubChem SID: 24847185; 24866944; 162091256
• PubChem CID: 10738

理论计算性质

• 质子受体: 2
• 质子供体: 1
• LogD (pH = 5.5): 2.703729
• LogD (pH = 7.4): 2.8631644
• Log P: 2.8656
• 摩尔折射率: 69.3476 cm^3
• 极化性: 22.537434 Å^3
• 极化表面积: 29.26 Å^2
• 可自由旋转的化学键: 2
• 里宾斯基五规则: true

分子性质

理化性质

• 熔点: 162-166 °C (dec.); ca 163°C dec.

安全信息

• 保存条件: Room Temperature (15-30°C)
• RTECS编号: MV3520000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); X
• 联合国危险货物编号: 3261
• 德国WGK号: 3
• 联合国危险货物等级: 8
• 联合国危险货物包装类别(PG): 2
• 危险公开号: 20/21/22-34; 22-36/37/38
• 安全公开号: 26-36/37; 26-36/37/39-45
• TSCA收录: 是
• GHS危险品标识: GHS05; GHS06; GHS07
• GHS警示词: Danger
• GHS危险声明: H301-H315-H319-H335; H302-H312-H314-H332
• GHS警示性声明: P261-P301+P310-P305+P351+P338-P302+P352-P405-P501A; P280-P305 + P351 + P338-P310
• 个人保护装置: Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 3261 8/PG 2

产品相关信息

• 纯度: ≥97.0% (AT); 95+%; 97%; 98%
• 级别: technical
• 成盐信息: HCl
• 线性分子式: (C6H5)2NNH2 · HCl

详细说明

MP Biomedicals - 02150975

Hydrochloride

Sigma Aldrich - 114596

Other Notes
少量水分可引起熔点差别很大
包装
25 g in glass bottle

参考文献

• Water-soluble sugars can be isolated as their organic-soluble diphenylhydrazones. For an example, including regeneration of the sugar by exchange with formaldehyde, see: Org. Synth. Coll., 3, 101 (1955), Note 3.