hydrazine; sulfuric acid

• ChemBase编号: 102976
• 分子式: H6N2O4S
• 平均质量: 130.12364
• 单一同位素质量: 130.00482768
• SMILES: NN.OS(=O)(=O)O
• Canonical SMILES: OS(=O)(=O)O.NN
• InChI: InChI=1S/H4N2.H2O4S/c1-2;1-5(2,3)4/h1-2H2;(H2,1,2,3,4)
• InChIKey: ZGCHATBSUIJLRL-UHFFFAOYSA-N

名称和登记号

名称

• IUPAC标准名: hydrazine; sulfuric acid
• IUPAC传统名: diamine; sulfuric acid; hydrazine; sulfuric acid
• 别名: 硫酸肼; 硫酸肼, ACS; Hydrazinium sulfate; 肼 硫酸盐; Hydrazine Monosulfate; HYDRAZINE SULFATE; Hydrazine sulfate; Hydrazine sulfate, ACS; Hydrazine sulfate salt; Hydrazinium sulfate; Hydrazine sulfate salt; Hydrazine sulphate

登记号

• CAS号: 10034-93-2
• EC号: 233-110-4; 204-563-5
• MDL号: MFCD00044873
• Beilstein号: 8778859
• 默克索引号: 144772
• PubChem SID: 24869089; 24852935; 162089608; 24878375
• PubChem CID: 24842
• Chemspider ID: 23225
• 美国药典/FDA物质标识码: 1N369SAT01
• 维基百科标题: Hydrazine_sulfate

理论计算性质

• Acid pKa: -3.034349
• 质子受体: 4
• 质子供体: 2
• LogD (pH = 5.5): -5.569452
• LogD (pH = 7.4): -5.594027
• Log P: -0.841552
• 摩尔折射率: 13.7708 cm^3
• 极化性: 6.279968 Å^3
• 极化表面积: 74.6 Å^2
• 可自由旋转的化学键: 0
• 里宾斯基五规则: true

分子性质

理化性质

• 溶解度: 30 g/L (20°C) in water
• 外观: Crystalline
• 熔点: 254 °C(lit.); 254°C; 254°C; ca 255°C dec.
• 密度: 1.370; 1.370 g/ml

安全信息

• 保存条件: Room Temperature (15-30°C)
• RTECS编号: MV9625000; MW2625000
• 欧盟危险性物质标志: 腐蚀性(Corrosive) (C); 环境危害性(Nature polluting) (N); 有毒(Toxic) (T); 有害性(Harmful) (Xn)
• 联合国危险货物编号: 1759; 2923; 3077; UN3288
• 德国WGK号: 3
• 联合国危险货物等级: 6.1; 8; 9
• 联合国危险货物包装类别(PG): 3; II; III
• 澳大利亚Hazchem: 2X
• 危险公开号: 45-22-50/53; 45-23/24/25-43-50/53; R:22-34-45
• 安全公开号: 53-45-60-61; S:27/28-29-36/37/39-45-53
• 欧盟危险货物分类: C10
• 欧盟危险识别号(EUHIN): 8B
• 美国ERG指导号: 154
• TSCA收录: 是
• 欧盟危险品索引: 007-008-00-3
• GHS危险品标识: GHS06; GHS07; GHS08; GHS09
• GHS警示词: Danger
• GHS危险声明: H301-H311-H317-H331-H350-H410; H301-H311-H331-H317-H350-H400-H410; H302-H350-H410
• GHS警示性声明: P201-P261-P273-P280-P301 + P310-P311; P201-P273-P308 + P313-P501; P261-P301+P310-P361-P302+P352-P405-P501A
• 个人保护装置: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges; dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges; Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• RID/ADR: UN 2923 8/PG 3; UN 3077 9/PG 3

产品相关信息

• 纯度: ≥97.0%; ≥98.0% (RT); ≥99% (iodometric); ≥99.0%; 97%; 99.0% min; 99.999% trace metals basis; 99+%
• 级别: ACS reagent; JIS special grade; puriss. p.a.; purum p.a.; SAJ first grade
• 燃烧残渣: ≤0.05%; ≤0.05% (as SO4)
• 杂质: ≤0.0005% heavy metals (as Pb); ≤0.005% insolubles
• 痕量阳离子: Cd: ≤5 mg/kg; Cd: ≤50 mg/kg; Co: ≤5 mg/kg; Co: ≤50 mg/kg; Cr: ≤5 mg/kg; Cu: ≤5 mg/kg; Cu: ≤50 mg/kg; Fe: ≤0.001%; Fe: ≤10 mg/kg; Fe: ≤5 mg/kg; Fe: ≤50 mg/kg; heavy metals (as Pb): ≤0.002%; K: ≤100 mg/kg; K: ≤50 mg/kg; Mg: ≤5 mg/kg; Mn: ≤5 mg/kg; Na: ≤100 mg/kg; Na: ≤50 mg/kg; NH4+: ≤400 mg/kg; Ni: ≤5 mg/kg; Ni: ≤50 mg/kg; Pb: ≤5 mg/kg; Pb: ≤50 mg/kg; Zn: ≤5 mg/kg; Zn: ≤50 mg/kg
• 痕量阴离子: chloride (Cl-): ≤0.005%; chloride (Cl-): ≤5 mg/kg; chloride (Cl-): ≤50 mg/kg
• 线性分子式: NH2NH2 · H2SO4

详细说明

MP Biomedicals - 02150130

Crystalline
Reagent for determination of C-terminal amino acids.

Sigma Aldrich - 455865

包装
25 g in poly bottle

Sigma Aldrich - 216046

包装
100, 500 g in poly bottle
5 g in glass bottle

参考文献

• Reagent for determination of C-terminal amino acid in peptides: Biochem. J ., 68, 475 (1958).